(R)-4,4’-Bis(Bis(3,5-Dimethylphenyl)Phosphino)-2,2’,6,6’-Tetramethoxy-3,3’-Bipyridine (R)-2,2’,6,6’-四甲氧基-4,4’-联(二(3,5-二甲苯基基)膦基)-3,3’-二联吡啶

CAS 442905-33-1 MFCD04974235

化学结构图

442905-33-1
SMILES: COc1cc(P(c2cc(C)cc(C)c2)c2cc(C)cc(C)c2)c(-c2c(P(c3cc(C)cc(C)c3)c3cc(C)cc(C)c3)cc(OC)nc2OC)c(OC)n1

化学属性

Melting Point190-194 °C
TSCANo
Mol. FormulaC46H50N2O4P2
Appearance white to pale yellow pwdr.
Mol. Weight757

别名和识别编码

Chemical Name(R)-4,4’-Bis(Bis(3,5-Dimethylphenyl)Phosphino)-2,2’,6,6’-Tetramethoxy-3,3’-Bipyridine
Synonym (S)-Xylyl-P-Phos (R)-Xylyl-P-Phos (R)-(+)-2,2′,6,6′-四甲氧基-4,4′-双(二(3,5-二甲苯基)膦-3,3′-联吡啶 (S)-(-)-2,2′,6,6′-四甲氧基-4,4′-双(二(3,5-二甲苯基)膦-3,3′-联吡啶
PubChem Substance ID24885316
Chemical Name Translation(R)-2,2’,6,6’-四甲氧基-4,4’-联(二(3,5-二甲苯基基)膦基)-3,3’-二联吡啶
InChIKeyJRTHAKOHBMETRC-UHFFFAOYSA-N
MDL NumberMFCD04974235
CAS Number442905-33-1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands, Privileged Lig

相关文献及参考

  • 1. Acc. Chem. Res. 39 , 711, (2006) 摘要
  • Merck 14 ,10462

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. P-Phos, PhanePhos and BoPhoz Ligands - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

相关产品推荐