2-Fluoro-4-Methylphenylboronic Acid 2-氟-4-甲基苯硼酸

CAS 170981-26-7 MFCD05664239

化学结构图

170981-26-7
SMILES: CC1C=CC(B(O)O)=C(F)C=1

化学属性

Mol. FormulaC7H8BFO2
Mol. Weight154
Melting Point228-233
TSCANo
Density1.2

别名和识别编码

Chemical Name2-Fluoro-4-Methylphenylboronic Acid
CAS Number170981-26-7
Alfabeta NameFLUOROMETHYLPHENYLBORONICACID 24---
MDL NumberMFCD05664239
Synonym 2-FLUORO-4-METHYLBENZENEBORONIC ACID Boronic acid, (2-fluoro-4-methylphenyl)- (9CI) 2-FLUORO-4-METHYLPHENYLBORONIC ACID 4-Methyl-2-fluorophenylboronic acid (2-Fluoro-4-methylphenyl)boronic Acid 2-氟-4-甲基苯硼酸 4-Methyl-2-fluorophenylboronic Acid 2-氟-4-甲基苯基硼酸 2-Fluoro-4-methylphenylboronic acid ,97% 2-Fluoro-4-methylphenylboronic acid 2-Fluoro-4-Methylphenylboronic 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride)
PubChem Substance ID87560954
Reaxys-RN10427096
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation2-氟-4-甲基苯硼酸
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Chai, D. I.; Lautens, M., Tandem Pd-Catalyzed Double C-C Bond Formation: Effect of Water J. Org. Chem. 74 , 3054-3061, (2009)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard Codes Xi

其他信息

  • MOL 文件:170981-26-7.mol
  • Sigma Aldrich:170981-26-7(sigmaaldrich)
  • 2-氟-4-甲基苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 F0683 2-氟-4-甲基苯硼酸(含有数量不等的酸酐) 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 5G 1870元 2011/04/16 F0683 2-氟-4-甲基苯硼酸(含有数量不等的酸酐) 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 1G 623元
  • Hazard Note:Irritant
  • 存储注意事项:氮气保护
  • 上游原料:四氢呋喃 --> 正丁基锂 --> 硼酸三异丙酯 --> 4-溴-3-氟甲苯
  • 检测方法:HPLC,NMR

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Disubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Functional Group 官能团索引
  2. boronic acid

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