Phosphorothioic Acid, O-[(Cyanophenylmethylene)Azanyl] O,O-Diethyl Ester 辛硫磷

CAS 14816-18-3 MFCD00867617

化学结构图

14816-18-3
SMILES: CCOP(=S)(O/N=C(\C#N)/C1C=CC=CC=1)OCC

化学属性

Mol. FormulaC12H15N2O3PS
Mol. Weight298.32

别名和识别编码

Chemical NamePhosphorothioic Acid, O-[(Cyanophenylmethylene)Azanyl] O,O-Diethyl Ester
MDL NumberMFCD00867617
PubChem Substance ID24862284
EC Number238-887-3
Synonym O,O-Diethyl-alpha-cyanobenzylidineaminooxyphosphonothiate Bayer 77488 BAY 77488 O,O-Diethyl O-(alpha-cyanobenzylideneamino)phosphorothioate; 4-Ethoxy-7-phenyl-3,5-dioxa-6-aza-4-phosphaoct-6-ene-8-nitrile 4-sulfide; alpha-[[(Diethoxyphosphinothioyl)oxy]imino]benzeneacetonitrile Benzoyl cyanide O-(diethoxyphosphinothioyl)oxime B 77488 O,O-Diaethyl-O-(alpha-cyanbenzyliden-amino)-thionphosphat 辛硫磷 Benzeneacetonitrile, alpha-(((diethoxyphosphinothioyl)oxy)imino)- alpha-(((Diethoxyphosphinothioyl)oxy)imino)benzeneacetonitrile BAY sra 7502 O,O-Diaethyl-O-(alpha-cyano-benzylidenamino)-monothiophosphat O,O-Diethyl phosphorothioate, O-ester with phenylglyoxylonitrile oxime BAY 5621 3,5-Dioxa-6-aza-4-phosphaoct-6-ene-8-nitrile, 4-ethoxy-7-phenyl-, Baythion (Diethoxy-thiophosphoryloxyimino)-phenyl acetonitrile
CAS Number14816-18-3
Chemical Name Translation辛硫磷
Wiswesser Line NotationNCYR&UNOPS&O2&O2
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Insecticides, N-P, Organophorous, P, PER - POLA, Pesticides & Metabolites, Pesticides Standards
  • {SNA} Analytical Standards, Insecticides, N-P, Organophorous, 农残和代谢标准品, 分析/色谱, 按照字母排序

安全信息

RTECSMD4740000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+P233
Hazard statements
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
WGK Germany3
Signal word Danger Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn;N Xn,N
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
UN Number 2810
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 5,181,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BWHOA6 Bulletin of the World Health Organization.  (WHO, Pub. Center USA, 49
   Sheridan Ave., Albany, NY 12210)  Volume(issue)/page/year: 44,31,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat

{hazard_com

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1050 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   52OLAC "Veterinarnaya Entomologiya i Akarologiya," Veterinary Entomology and
   Acarology, Nepoklonov, A.A., ed., Moscow, Izdatel'stovo Kolos, 1983
   Volume(issue)/page/year: -,230,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2576 mg/kg
SEX/DURATION            : male 8 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   DDTWDG DTW, Deutsche Tieraerztliche Wochenschrift.  (Verlag M. & H. Schaper,
   Postfach 1642, D-31061 Alfeld (Leine), Germany)  V.78-    1971-
   Volume(issue)/page/year: 102,301,1995

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 49 mg/kg
SEX/DURATION            : male 74 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 45(7),77,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2760 mg/kg
SEX/DURATION            : male 60 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
REFERENCE :
   DDTWDG DTW, Deutsche Tieraerztliche Wochenschrift.  (Verlag M. & H. Schaper,
   Postfach 1642, D-31061 Alfeld (Leine), Germany)  V.78-    1971-
   Volume(issue)/page/year: 102,301,1995

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1380 mg/kg
SEX/DURATION            : male 60 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and c

系列性分类


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