(R)-BINAPHANE

CAS 253311-88-5 MFCD06658114

化学结构图

253311-88-5
SMILES: C1C2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2CP1C1=CC=CC=C1P1CC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2C1

化学属性

Mol. FormulaC50H36P2
Mol. Weight698.77
Melting Point>;200 °C (dec.)

别名和识别编码

Chemical Name(R)-BINAPHANE
Synonym (R)-联萘
MDL NumberMFCD06658114
PubChem Substance ID24883783
CAS Number253311-88-5
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes

相关文献及参考

  • 1. H. Yamamoto, et al., , Hg(OTF)2-BINAPHANE-catalyzed enantioselective anilino sulfonamide allyl alcohol cyclization Chem. Eur. J. 16 , 11271-11274, (2010)
  • 2. C. Benhaim, et al., , Enantioselective Synthesis of ß-Trifluoromethyl a-Amino Acids Org. Lett. 12 , 2008-2011, (2010)
  • 3. M. Mondal, et al., , Phosphine-Catalyzed Asymmetric Synthesis of ß-Lactones from Arylketoketenes and Aromatic Aldehydes Org. Lett. 12 , 1664-1667, (2010)
  • 4. A. A. Ibrahim, et al., , Organocatalytic Dimerization of Ketoketenes J. Org. Chem. 74 , 1777-1780, (2009)
  • 5. H. Luo, et al., , Palladium(II) Complexes of C2-Bridged Chiral Diphosphines: Application to Enantioselective Carbonyl-Ene Reactions Adv. Synth. Catal. 352 , 1356-1364, (2010)
  • 6. Xiao, D. et al. Org. Lett. 1 , 1679, (1999) 摘要

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类


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