R-(-)-1 13-Bis(Diphenylphosphino)-7 8-Dihydro-6H-Dibenzo[F H][1 5]Dioxonin (R)-C3-Tunephos (R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷

CAS 301847-89-2 MFCD06658115

化学结构图

301847-89-2
SMILES: C1CCOC2C=CC=C(C=2C2C(=CC=CC=2O1)P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC39H32O2P2
Mol. Weight594.62
Melting Point153-161 °C(lit.)
Appearance white pwdr.
Stabilityair sensitive

别名和识别编码

Chemical NameR-(-)-1 13-Bis(Diphenylphosphino)-7 8-Dihydro-6H-Dibenzo[F H][1 5]Dioxonin (R)-C3-Tunephos
Synonym (R)-(-)-1,13-二(二苯基膦)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬四烯 (R)-C3-TunePhos
MDL NumberMFCD06658115
PubChem Substance ID24883784
CAS Number301847-89-2
Chemical Name Translation(R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes

相关文献及参考

  • 1. Li, W.; et al., Highly Efficient and Highly Enantioselective Asymmetric Hydrogenation of Ketones with TunePhos/1,2-Diamine-Ruthenium(II) Complexes J. Org. Chem. 74 , 1397-1399, (2009)
  • 2. Wu, S.; et al., Highly Enantioselective Hydrogenation of Enol Acetates Catalyzed by Ru-TunaPhos Complexes Org. Lett. 4 , 4495-4497, (2002)
  • 3. Kim, I. S.; et al., Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition J. Am. Chem. Soc. 130 , 14891-14899, (2008)
  • 4. Wang, C.-J.; et al., Highly enantioselective hydrogenation of a-keto esters catalyzed by Ru-tunephos complexes Synlett , 1169-1172, (2006)
  • 5. Zhang, Z. et al. J. Org. Chem. 65 , 6223, (2000) 摘要
  • 6. Tang, W. et al. J. Am. Chem. Soc. 125 , 9570, (2003) 摘要
  • 7. Lei, A. et al. J. Am. Chem. Soc. 126 , 1626, (2004) 摘要

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Chiral Quest Ligands and Complexes - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Chiral Quest Ligands and Complexes - Privileged Ligands and Complexes
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Catalysts
  2. 96-5900 Chiral Quest Catalyst and Ligand Toolbox Kit for Asymmetric Hydrogenation
  1. Ligands
  2. 96-5900 Chiral Quest Catalyst and Ligand Toolbox Kit for Asymmetric Hydrogenation
  1. Phosphine
  2. 96-5900 Chiral Quest Catalyst and Ligand Toolbox Kit for Asymmetric Hydrogenation

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