1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]diphenylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate ((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)

CAS 405235-55-4 MFCD06658140

化学结构图

405235-55-4
SMILES: [Ir+].C[C@@H]1OC(=N[C@@H]1C(CC1=CC=CC=C1)(CC1=CC=CC=C1)OP(C1=CC=CC=C1)C1=CC=CC=C1)C1=CC=CC=C1.FC(F)(F)C1=CC(=CC(=C1)[B-](C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C(F)(F)F.C1C[CH][CH]CC[CH][CH]1 |^1:101,102,105,106|

化学属性

Mol. FormulaC77H58BF24IrNO2P
Mol. Weight1719.25
Appearance orange pwdr.
Stabilityair sensitive, store cold
Melting Point112-113°C

别名和识别编码

Chemical Nametetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (S,S)-[COD]Ir[Ph2PThrePHOX]
Synonym ThrePHOX ThrePHOX Ubaphox [((4S,5S)-Ph2-Ubaphox)Ir(COD)]BARF Ubaphox [((4S,5S)-Ph2-Ubaphox)Ir(COD)]BARF
MDL NumberMFCD06658140
PubChem Substance ID329761386
CAS Number405235-55-4
Chemical Name Translation((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, PHOX, Privileged Ligands and Complexes, Solvias Ligands and Complexes, Ubaphox

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. ThrePHOX
  2. Iridium
  1. Catalysts
  2. Iridium

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