RcSp-DuanPhos (1R,1’R,2S,2’S)-2,2’-二叔丁基-2,3,2’,3’-四氢-1H,1’H-(1,1’)二异磷哚
CAS 528814-26-8 MFCD07781993
化学结构图
SMILES: CC(C)(C)P1CC2C=CC=CC=2[C@@H]1[C@H]1C2C=CC=CC=2CP1C(C)(C)C
化学属性
| Mol. Formula | C24H32P2 |
|---|---|
| Mol. Weight | 382.46 |
| Melting Point | 214-246 °C |
| Appearance | white xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | RcSp-DuanPhos |
|---|---|
| Synonym | (1R,1′R,2S,2′S)-DuanPhos (1R,1′R,2S,2′S)-2,2′-二叔丁基-2,3,2′,3′-四氢-1H,1′H-(1,1′)二异磷哚 |
| PubChem Substance ID | 24884305 |
| CAS Number | 528814-26-8 |
| Chemical Name Translation | (1R,1’R,2S,2’S)-2,2’-二叔丁基-2,3,2’,3’-四氢-1H,1’H-(1,1’)二异磷哚 |
| MDL Number | MFCD07781993 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
相关文献及参考
- 1. Kinderman, S. S.; et al., Phosphine-catalyzed [3 + 2] annulation of cyanoallenes Synlett , 1693-1696, (2011)
- 2. Gonzalez-Rodriguez, C.; et al., Rhodium-catalyzed intermolecular alkyne hydroacylation: the enantio- selective synthesis of α- and β-substituted ketones by kinetic resolution Chem. Eur. J. 16 , 10950-10954, (2010)
- 3. Ma, M.; et al., Highly efficient RhI-catalyzed asymmetric hydrogenation of β-amino acrylonitriles Chem. Eur. J. 16 , 5301-5304, (2010)
- 4. Geng, H.; et al., Rhodium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of β-Ketoenamides: Efficient Access to anti 1,3-Amino Alcohols Angew. Chem. Int. Ed. Engl. 48 , 6052-6054, (2009)
- 5. Guan, Z.-H.; et al., Synthesis of enamides via Rh/C-catalyzed direct hydroacylation of ketoximes Org. Lett. 11 , 481-483, (2009)
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