(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN (1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE

CAS N/A MFCD07782007

化学结构图

N/A
SMILES: [Rh+].CC(C)(C)P1CC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2[C@H]1[C@@H]1C2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2CP1C(C)(C)C.F[B-](F)(F)F.C1CC=CCCC=C1

化学属性

Mol. FormulaC52H48P2.C8H12.BF4.Rh
Mol. Weight1032.78
Melting Point>;300 °C

别名和识别编码

Chemical Name(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN (1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
Synonym [(S)-二叔丁基四氢联二萘磷(环辛二烯)铑(I)]四氟硼酸盐
MDL NumberMFCD07782007
PubChem Substance ID24884435
CAS Number1046806-02-3
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes

相关文献及参考

  • 1. Tang, W. et al Angew. Chem. Int. Ed. Engl. 42 , 3509, (2003)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Chiral Quest Ligands and Complexes - Privileged Ligands and Complexes

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