(S)-Ru(Oac)2(Binap) 二乙酸根[(S)-(+)-2,2′-二(二苯基膦基)-1,1′-联萘基]钌(II)
CAS 261948-85-0 MFCD09753020
化学结构图
SMILES:
化学属性
| Mol. Formula | C48H38O4P2Ru |
|---|---|
| Mol. Weight | 842 |
| Appearance | pale yellow pwdr. |
| Stability | air sensitive |
| Melting Point | >100°C dec. |
别名和识别编码
| Chemical Name | (S)-Ru(Oac)2(Binap) |
|---|---|
| Synonym | (R)-Ru(OAc)2(BINAP) 二乙酸根[(R)-(+)-2,2′-二(二苯基膦基)-1,1′-联萘基]钌(II) 二乙酸根[(S)-(+)-2,2′-二(二苯基膦基)-1,1′-联萘基]钌(II) |
| Chemical Name Translation | 二乙酸根[(S)-(+)-2,2′-二(二苯基膦基)-1,1′-联萘基]钌(II) |
| MDL Number | MFCD09753020 |
| CAS Number | 261948-85-0 |
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分类
- {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
相关文献及参考
- Denmark, S. E.; et al., Total synthesis of (+)-papulacandin D Tetrahedron 66 , 4745-4759, (2010)
- Beghetto, V.; et al., Synthesis of Chiraphos via asymmetric hydrogenation of 2,3-bis(diphenylphosphinoyl)buta-1,3-diene Chem. Commun. , 155-156, (2000)
- Li, Y.; Izumi, T., Asymmetric synthesis of chiral d-lactones using BINAP-ruthenium(II) complex hydrogenation catalysts J. Chem. Res. Synop. , 567-569, (2002)
- Tsukamoto, M.; et al., Mechanism of catalytic asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline using Ru(CH3COO)2[(S)-binap] Tetrahedron 62 , 5448-5453, (2006)
- Li, Y.; Izumi, T., A novel asymmetric reduction of nitroolefin 2-nitro-1-phenyl-1-propene by using BINAP-ruthenium(II) complexes J. Chem. Res. Synop. , 128-129, (2003)
- Wang, Y.; Metz, P., A General Access to Zaragozic Acids: Total Synthesis and Structure Elucidation of Zaragozic Acid D and Formal Syntheses of Zaragozic Acids A and C Chem. Eur. J. 17 , 3335-3337, (2011)
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