(R)-Ru(OAc)2(DM-SEGPHOS®)

CAS N/A MFCD09753025

化学结构图

N/A
SMILES: CC(=O)O[Ru]OC(C)=O.CC1=CC(C)=CC(=C1)P(C1C=CC2OCOC=2C=1C1C2OCOC=2C=CC=1P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1

化学属性

Mol. FormulaC50H50O8P2Ru
Mol. Weight941.94

别名和识别编码

Chemical Name(R)-Ru(OAc)2(DM-SEGPHOS®)
Synonym 二乙酸根[(R)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II) (S)-Ru(OAc)2(DM-SEGPHOS®)
MDL NumberMFCD09753025
CAS Number944450-50-4
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS

相关文献及参考

  • Steinhuebel, D.; et al., Direct Asymmetric Reductive Amination J. Am. Chem. Soc. 131 , 11316-11317, (2009)

安全信息

WGK Germany3
Hazard Codes Xi
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SEGPHOS® - Privileged Ligands and Complexes

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