[1,1′-(1R)-[1,1′-Binaphthalene]-2,2′-Diylbis[1,1-Bis(3,5-Dimethylphenyl)Phosphine-Κp]]Dichloro[(1R,2R)-1,2-Diphenyl-1,2-Ethanediamine-Κn1,Κn2]Ruthenium [(R)-2,2’-双[二(3,5-二甲基苯基)膦]-1,1’-联萘][(1R,2R)-1,2-二苯基乙二胺]二氯化钌

CAS 220114-38-5 MFCD09753028

化学结构图

220114-38-5
SMILES: CC1=CC(C)=CC(=C1)P(C1C=CC2C=CC=CC=2C=1C1C2C=CC=CC=2C=CC=1P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1.N[C@@H]([C@H](N)C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ru]Cl

化学属性

Mol. FormulaC66H64Cl2N2P2Ru
Mol. Weight1119.15
Appearance yellow pwdr.
Stabilityair sensitive
Danger-Level
pH:
Redox

别名和识别编码

Chemical Name[1,1′-(1R)-[1,1′-Binaphthalene]-2,2′-Diylbis[1,1-Bis(3,5-Dimethylphenyl)Phosphine-Κp]]Dichloro[(1R,2R)-1,2-Diphenyl-1,2-Ethanediamine-Κn1,Κn2]Ruthenium
Synonym 二氯[(R)-(+)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(1R,2R)-(+)-1,2-二苯基乙烯二胺]钌(II) RuCl2[(R)-DM-BINAP][(R,R)-DPEN]
MDL NumberMFCD09753028
CAS Number220114-38-5
Chemical Name Translation[(R)-2,2’-双[二(3,5-二甲基苯基)膦]-1,1’-联萘][(1R,2R)-1,2-二苯基乙二胺]二氯化钌
PubChem Substance ID329761481
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

安全信息

WGK Germany3
Restrict

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. BINAP
  2. Ruthenium
  1. BINAP
  2. 96-6954 Takasago BINAP Ru Diamine Catalyst Kit
  1. Catalysts
  2. 96-6954 Takasago BINAP Ru Diamine Catalyst Kit
  1. Catalysts
  2. Ruthenium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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