Dimethylammonium DiChlorotri(μ-Chloro)Bis[(S)-(-)-2,2-Bis(di-p-Tolylphosphino)-1,1-Binaphthyl]Diruthenate(II) 二甲基铵二氯三(μ-氯)双[(S)-(-)-2,2’-双(二-对甲苯基膦基)-1,1’-联萘基]二钌(II)

CAS 309735-86-2 MFCD09753034

化学结构图

309735-86-2
SMILES:

化学属性

Mol. Formula(CH3)2NH2+[C96H80Cl5P4Ru2]-
Mol. Weight1783.05
Appearance brown pwdr.
Stabilityair sensitive
Melting Point>100°C dec.

别名和识别编码

Chemical NameDimethylammonium DiChlorotri(μ-Chloro)Bis[(S)-(-)-2,2-Bis(di-p-Tolylphosphino)-1,1-Binaphthyl]Diruthenate(II)
Synonym 二甲铵二氯三(μ-氯)双[(R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘基]二钌酸盐(II) 二甲铵二氯三(μ-氯)双[(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘基]二钌酸盐(II) (S)-[(RuCl (T-BINAP))2(μ-Cl)3[NH2Me2]
MDL NumberMFCD09753034
CAS Number309735-86-2
Chemical Name Translation二甲基铵二氯三(μ-氯)双[(S)-(-)-2,2’-双(二-对甲苯基膦基)-1,1’-联萘基]二钌(II)
PubChem Substance ID253660982
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P308+P311
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H228 Flammable solid 易燃固体
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Warning
Hazard Codes F
Risk Statements
  • R11 Highly flammable 非常易燃

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. BINAP
  2. Ruthenium
  1. BINAP
  2. 96-6952 Takasago BINAP Ru Dimer Catalyst Kit
  1. Catalysts
  2. 96-6952 Takasago BINAP Ru Dimer Catalyst Kit
  1. Catalysts
  2. Ruthenium

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