(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷

CAS 447440-43-9 MFCD09953823

化学结构图

447440-43-9
SMILES: C[C@H]1[C@@H](O[Si](Cl)(CC=C)N1C)C1C=CC=CC=1

化学属性

Density1.095 g/mL at 25 °C
Boiling Point120 °C/5 mmHg
Refractive indexn20/D 1.517
Mol. FormulaC13H18ClNOSi
Mol. Weight267.83
Appearance colorless oil
Stabilitymoisture sensitive, store cold

别名和识别编码

Chemical Name(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane
Synonym (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1,3,2-氧氮杂硅杂环戊烷 (1S,2S)-伪麻黄碱烯丙基氯硅烷 (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷 (1S,2S)-伪麻黄碱烯丙基氯硅烷 (4S,5S)-2-氯-3,4-二甲基-5-苯基-2-(2-丙烯基)-1-氧杂-3-氮杂-2-硅杂环戊烷 (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1,3,2-氧氮杂硅杂环戊烷 (4S,5S)-2-氯-3,4-二甲基-5-苯基-2-(2-丙烯基)-1-氧杂-3-氮杂-2-硅杂环戊烷
Chemical Name Translation(4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷
PubChem Substance ID329762661
MDL NumberMFCD09953823
CAS Number447440-43-9
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分类

  • {SNA} Allylation, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P305+P351+P338
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard Codes F,Xi
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Allylation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Organocatalyst
  2. Silicon
  1. Catalysts
  2. Silicon

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