(R,R,S)-DIAZAPHOS-PPE 2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]

CAS 615257-74-4 MFCD10566993

化学结构图

615257-74-4
SMILES: C[C@H](NC(=O)C1=CC=CC=C1[C@@H]1N2C(=O)C3C=CC=CC=3C(=O)N2[C@@H](C2=CC=CC=C2C(=O)N[C@@H](C)C2C=CC=CC=2)P1C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC46H39N4O4P
Mol. Weight742.80
Melting Point258-262 °C

别名和识别编码

Chemical Name(R,R,S)-DiazaPhos-PPE
Synonym (R,R,S)-DiazaPhos-PPE 2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]
MDL NumberMFCD10566993
CAS Number615257-74-4
Chemical Name Translation2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]
PubChem Substance ID329760941
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroformylation, Landis Ligands, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroformylation, Landis Ligands, Privileged Ligands and Complexes

相关文献及参考

  • 1. Axtell, A.T. et al. Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005) 摘要
  • 2. Clark, T.P. et al. J. Am. Chem. Soc. 127 , 5040, (2005) 摘要

安全信息

WGK Germany3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Landis Ligands - Privileged Ligands and Complexes

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