2,2',2'',2'''-(1,2-PHENYLENEBIS[(1S,3S)-TETRAHYDRO-5,8-DIOXO-1H-[1,2,4]DIAZAPHOSPHOLO[1,2-A]PYRIDAZINE-2,1,3(3H)-TRIYL])TETRAKIS(N-[(1S)-1-PHENYLETHYL])BENZAMIDE 2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-a]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺

CAS 851770-14-4 MFCD10566996

化学结构图

851770-14-4
SMILES: C[C@H](NC(=O)C1=CC=CC=C1[C@H]1N2C(=O)CCC(=O)N2[C@H](C2=CC=CC=C2C(=O)N[C@@H](C)C2C=CC=CC=2)P1C1=CC=CC=C1P1[C@@H](C2=CC=CC=C2C(=O)N[C@@H](C)C2C=CC=CC=2)N2C(=O)CCC(=O)N2[C@@H]1C1=CC=CC=C1C(=O)N[C@@H](C)C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC78H72N8O8P2
Mol. Weight1311.40
Melting Point289-299 °C

别名和识别编码

Chemical NameBis[(S,S,S)-DiazaPhos-SPE]
Synonym Bis[(S,S,S)-DiazaPhos-SPE] 2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-a]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺
MDL NumberMFCD10566996
CAS Number851770-14-4
Chemical Name Translation2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-a]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺
PubChem Substance ID329760956
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroformylation, Landis Ligands, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroformylation, Landis Ligands, Privileged Ligands and Complexes

相关文献及参考

  • 1. Watkins, A. L.; Landis, C. R. , Regioselective rhodium-catalyzed hydroformylation of 1,3-dienes to highly enantioenriched β,γ-unsaturated aldehydes with diazaphospholane ligands Org. Lett. 13 , 164-167, (2011)
  • 2. McDonald, R. I.; et al., Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands J. Am. Chem. Soc. 132 , 14027-14029, (2010)
  • 3. Watkins, A. L.; Landis, C. R., Origin of Pressure Effects on Regioselectivity and Enantioselectivity in the Rhodium-Catalyzed Hydroformylation of Styrene with (S,S,S)-BisDiazaphos J. Am. Chem. Soc. 132 , 10306-10317, (2010)
  • 4. Noonan, G. M.; et al., Regioselective and Enantioselective Hydroformylation of Dialkylacrylamides Adv. Synth. Catal. 352 , 1047-1054, (2010)
  • 5. Watkins, A. L.; et al., Highly Enantioselective Hydroformylation of Aryl Alkenes with Diazaphospholane Ligands Org. Lett. 10 , 4553-4556, (2008)
  • 6. Owens, S. B., Jr.; Gray, G. M., Study of the Effects of Alkali Metal Salts on Styrene Hydroformylation Reactions Catalyzed by Rhodium(I) Complexes of Bis(phosphite) Ligands Organometallics 27 , 4282-4287, (2008)
  • 7. Axtell, A.T. et al. Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005) 摘要
  • 8. Clark, T.P. et al. J. Am. Chem. Soc. 127 , 5040, (2005) 摘要

安全信息

WGK Germany3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Landis Ligands - Privileged Ligands and Complexes

相关产品推荐