Perfluorooctanoic acid 全氟辛酸

CAS 335-67-1 MFCD00004174

化学结构图

335-67-1
SMILES: O=C(O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC8HF15O2
Mol. Weight414.07
Boiling Point189°C(lit.)
Melting Point55-56
TSCAT
Density1.8
Solubility3.4 G/L
Stability对光敏感
Flash Point189-192°C
Appearance 白色晶体。 在32℃水中的溶解度为0.01~0.023mol/L。

别名和识别编码

Chemical NamePerfluorooctanoic acid, 99.5%, reference material
CAS Number335-67-1
Alfabeta NamePENTADECAFLUOROOCTANOICACID
MDL NumberMFCD00004174
Synonym APFO PFOA cpd PFOA perfluorooctanoic acid ammonium perfluorooctanoate pentadecafluorooctanoic acid perfluorinated octanoic acid perfluorooctanoate perfluorooctanoic acid perfluorooctanoic acid, anhydride perfluorooctanoic acid, cesium salt perfluorooctanoic acid, chromium (3+) salt perfluorooctanoic acid, cobalt (2+) salt perfluorooctanoic acid, lithium salt perfluorooctanoic acid, monoammonium salt perfluorooctanoic acid, monopotassium salt perfluorooctanoic acid, monosilver (1+) salt perfluorooctanoic acid, monosodium salt perfluorooctanoyl chloride potassium pentadecafluorooctanoate potassium perfluorooctanoate silver perfluorooctanoate silver(1+) pentadecafluorooctanoate sodium sodium perfluorooctanoate {} {} {} Pentadecaf
Beilstein Registry Number1809678
EC Number206-397-9
Reaxys-RN1809678
PubChem Substance ID9554
Chemical Name Translation全氟辛酸
Wiswesser Line NotationQVXFFXFFXFFXFFXFFXFFXFFF
LabNetwork Molecule IDLN00117329
InChIInChI=1S/C8HF15O2/c9-2(10,1(24)25)3(11,12)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)23/h(H,24,25)
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分类

  • Analytical Standards,
  • {SNA} Analytical Standards, Chemical Class, Chromatography, Drinking Water, Environmental Standards, Fluoro, Food & Beverage Standards, Food Residuals, Halogenated, Perfluorocarboxylates, 分析/色谱
  • {SNA} Chemical Synthesis, Fluorous Synthesis, Rf-Tagged Building Blocks and Precursors, Specialty Synthesis
  • {SNA} Additional Standards, Analytical Standards, Chemical Class, Chromatography, Drinking Water, ECHA SVHC, Environmental Standards, Fluoro, Food & Beverage Standards, Food Residuals, Food and Cosmetic Component Standards

产品应用

  • 被用作高效表面活性剂、分散剂、添加剂等。全氟辛酸及其衍生物作为重要的有机中间体可用于合成含氟憎水憎油剂、皮革整理剂等产品。

相关文献及参考

  • Beilstein: 2,IV,994

安全信息

Warnings IRRITANT, CORROSIVE
Precautionary statements
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P263 Avoid contact during pregnancy/while nursing. 怀孕/哺乳期间避免接触。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P316
  • P301+P317
  • P301+P330+P331
  • P302+P361+P354
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P316
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P337+P317
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSRH0781000
GHS Symbol
WGK Germany3
Signal word Danger
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H362 May cause harm to breast-fed children 可能对母乳喂养的婴儿造成伤害
  • H370 Causes damage to organs 导致器官损伤
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
Hazard Codes 8
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
UN Number 1760
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R52/53
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Packing GroupII
Storage condition 密封避光保存。 2-8°C 储存温度2-8℃,充氩保存
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 189 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   70,362,1983

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 50 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,95,1981

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 168 mg/kg/2W (Continuous)
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   57,55,1991

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   57,55,1991

其他信息

  • 海关编码:29159080
  • MSDS 信息:Pentadecafluorooctanoic acid(335-67-1).msds
  • Hazard Note:Corrosive
  • 方法一:将原料辛酰氯（纯度99.5%）与氟化氢及少量正丁基硫酸投入电解槽，于20-25℃下通电（电压5-8V），电解产物用碱中和，再用酸酸化，蒸馏之，即得全氟辛酸。原料消耗定额：辛酰氯6000-8000kg/t、天水氟化氢12000kg/t、硫酸1500kg/t、氢氧化钠1500kg/t。
  • TSCA:T
  • Acros Organics:全氟辛酸 Pentadecafluorooctanoic acid, 96%(335-67-1)
  • 全氟辛酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0764 十五氟辛酸水合物 Pentadecafluorooctanoic Acid Hydrate 10G 597元 2014/06/02 A5720 十五氟辛酸,高等级[用于液相色谱-质谱的离子对试剂] Pentadecafluorooctanoic Acid High Grade [Ion-Pair Reagent for LC-MS] 5G 2260元 2014/06/02 A5720 十五氟辛酸,高等级[用于液相色谱-质谱的离子对试剂] Pentadecafluorooctanoic Acid High Grade [Ion-Pair Reagent for LC-MS] 1G 756元
  • 全氟辛酸（FF61）是全氟碳一元羧酸，是一种有机强酸，具有低表面张力，高表面活性 等特性。
  • 用途二:主要用作表面活性剂、乳化剂、全氟辛酸及其钠盐或铵盐用于四氟乙烯聚合及氟橡胶生产时作分散剂，也用作制备增水、憎油剂的原料和选矿剂。
  • 图谱信息:全氟辛酸(335-67-1)质谱(MS) 全氟辛酸(335-67-1)红外图谱(IR2) 全氟辛酸(335-67-1)红外图谱(IR1)
  • 上游原料:氢氟酸 --> 辛酰氯
  • 用途三:被用作高效表面活性剂、分散剂、添加剂等。全氟辛酸及其衍生物作为重要的有机中间体可用于合成含氟憎水憎油剂、皮革整理剂等产品。
  • 下游产品:N-全氟辛酰基氨酸盐 --> 聚偏氟乙烯树脂 --> 聚氯三氟乙烯-偏氟乙烯共聚物
  • Sigma Aldrich:335-67-1(sigmaaldrich)
  • TCI Shanghai:十五氟辛酸水合物 Pentadecafluorooctanoic Acid Hydrate,>;98.0%(T)(335-67-1)
  • Alfa Aesar:全氟辛酸,95% Perfluorooctanoic acid, 95%(335-67-1)
  • MOL 文件:335-67-1.mol
  • 用途一:用作CTFE、TFE及氟橡胶聚合分散剂

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  4. Rf-Tagged Building Blocks and Precursors - Fluorous Synthesis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  6. C8 - Carboxylic Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Food & Beverage Standards - Chromatography
  5. Food Residue Analysis - Food & Beverage Standards
  6. Perfluorocarboxylates - Food Residue Analysis
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Analytical & Chromatography 分析化学与色谱
  2. Ion-Pair Reagents for HPLC
  1. Organo Fluorine
  2. Fluorine

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