(R,R)-ANDEN-Phenyl Trost Ligand (R,R)-ANDEN-苯基 Trost 配体
CAS 152140-65-3 MFCD12546007
化学结构图
SMILES: O=C(N[C@@H]1[C@@H]2C3C=CC=CC=3[C@H]([C@H]1NC(=O)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=12)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C54H42N2O2P2 |
|---|---|
| Mol. Weight | 812.87 |
| Melting Point | 125-130 °C |
别名和识别编码
| Chemical Name | (R,R)-ANDEN-Phenyl Trost Ligand |
|---|---|
| Synonym | (R,R)-ANDEN-苯基 Trost 配体 (+)-(11R,12R)双[2′-(二苯基膦)苯甲酰氨基]-9,10-二氢-9,10-乙基桥蒽 (11R,12R)-N,N′-(9,10-二氢-9,10-乙基桥蒽-11,12-二基)双[2-(二苯基膦)]-苯甲酰胺 (+)-(11R,12R)双[2′-(二苯基膦)苯甲酰氨基]-9,10-二氢-9,10-乙基桥蒽 (11R,12R)-N,N′-(9,10-二氢-9,10-乙基桥蒽-11,12-二基)双[2-(二苯基膦)]-苯甲酰胺 |
| MDL Number | MFCD12546007 |
| CAS Number | 152140-65-3 |
| Chemical Name Translation | (R,R)-ANDEN-苯基 Trost 配体 |
| PubChem Substance ID | 329761935 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
相关文献及参考
- 1. B. M. Trost and D. A. Thaisrivongs, , Strategy for Employing Unstabilized Nucleophiles in Palladium-Catalyzed Asymmetric Allylic Alkylations J. Am. Chem. Soc. 130 , 14092-14093, (2008)
- 2. B. M. Trost and J. Xu, , Palladium-Catalyzed Asymmetric Allylic a -Alkylation of Acyclic Ketones J. Am. Chem. Soc. 127 , 17180-17181, (2005)
- 3. B. M. Trost and W. Tang, , Migratory Hydroamination: A Facile Enantioselective Synthesis of Benzomorphans J. Am. Chem. Soc. 125 , 8744-8745, (2003)
- 4. Trost, B.M. et al. Chem. Rev. 96 , 395, (1996) 摘要
- 5. Trost, B.M. et al. Chem. Rev. 103 , 2921, (2003) 摘要
- 6. Trost, B.M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
- 7. Trost, B.M. et al. Aldrichimica Acta 40 , 59, (2007)
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