• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents
• {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Hypervalent Iodine, Oxidants, Oxidizing Agents, Synthetic Reagents

产品应用

• 铑催化烯烃氮杂环丙烷磺酸酯氧化剂。
• 在常温下使用钯催化吲哚的2 - 芳基化
• 各种各样的杂环化合物合成的有用的试剂。

相关文献及参考

• For use in the Pd(II)-catalyzed functionalization of sp2 and sp3 C-H bonds, see: J. Am. Chem. Soc., 126, 2300 (2004).
• For a review of the ɑ-functionalization of carbonyl compounds by hypervalent iodine reagents, see: Contemp. Org. Synth., 2, 121 (1995).
• In the presence of triethyl orthoformate, aryl ethyl ketones undergo a rearrangement to ɑ-methyl arylacetates: Synthesis, 231 (1984):
• In combination with iodine, forms the acyl hypoiodite, which adds to alkenes: Bull. Chem. Soc. Jpn., 41, 1476 (1968), iodinates alkylbenzenes: J. Am. Chem. Soc., 90, 6187 (1968), and effects the decarboxylative iodination of aromatic carboxylic acids: Synth. Commun., 18, 1327 (1988).
• Beilstein: 5,IV,693
• For a brief feature on uses of the reagent in synthesis, see: Synlett, 657 (2006). For reviews of the use of polyvalent iodine compounds in organic synthesis, see: Synthesis, 709 (1984); Acc. Chem. Res., 19, 244 (1986); Chem. Rev., 96, 1123 (1996). For a monograph, see: A Varvoglis, The Organic Chemistry of Polycoordinated Iodine, VCH, N.Y. (1992).
• Versatile oxidizing and acetoxylating agent.
• Similarly, in the presence of an orthoformate and sulfuric acid, flavanones undergo a 1,2-aryl shift to give 2-aryl-2,3-dihydrobenzofuran-3-carboxylates: Bull. Chem. Soc. Jpn., 68, 1168 (1995). However, iodosobenzene diacetate alone oxidizes flavanones to flavones: J. Chem. Res. (Synop.), 213 (1995). For a review of the use of the reagent in heterocyclic synthesis, see: Synlett, 221 (1994).
• Treatment with aqueous NaOH gives the useful selective oxidant iodosobenzene (iodosylbenzene): Org. Synth. Coll., 5, 658 (1973).
• Converts primary aliphatic amides to amines, by Hofmann degradation: J. Org. Chem., 44, 1746 (1979); Synthesis, 266 (1981); 31 (1983). For use in the s
• Useful reagent for mild, rapid cleavage of 1,3-dithianes to the parent carbonyl compounds: Syn. Commun., 30, 4081 (2000).
• For a brief feature on uses of

安全信息

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02976

其他信息

• Sigma Aldrich:3240-34-4(sigmaaldrich)
• MOL 文件:3240-34-4.mol
• 海关编码:29310095
• F:4.10-8
• 用途二:用作拓扑替康中间体
• 不溶于水。
• Acros Organics:二乙酸碘代苯 Iodobenzene diacetate, 98%(3240-34-4)
• Alfa Aesar:二乙酸亚碘酰苯,98+% Iodosobenzene diacetate, 98+%(3240-34-4)
• 碘苯二乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0330 碘苯二乙酸酯 Iodobenzene Diacetate 250G 1980元 2014/06/02 I0330 碘苯二乙酸酯 Iodobenzene Diacetate 10G 185元 2014/06/02 I0330 碘苯二乙酸酯 Iodobenzene Diacetate 25G 382元
• Hazard Note:Irritant
• MSDS 信息:(Diacetoxyiodo)benzene(3240-34-4).msds
• 上游原料:乙酸 --> 乙酐 --> 过氧化氢 --> 醋酸 --> 碘苯
• 检测方法:HPLC,NMR,TITR
• 用途一:氧化剂
• TCI Shanghai:碘苯二乙酸酯 Iodobenzene Diacetate,>;97.0%(T)(3240-34-4)
• 图谱信息:碘苯二乙酸(3240-34-4)红外图谱(IR1) 碘苯二乙酸(3240-34-4)红外图谱(IR2) 碘苯二乙酸(3240-34-4)质谱(MS) 碘苯二乙酸(3240-34-4)核磁图( 13 CNMR) 碘苯二乙酸(3240-34-4)核磁图( 1 HNMR)
• 存储注意事项:光敏感
• 碘苯二乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 I0330 碘苯二乙酸酯 Iodobenzene Diacetate 250G 4080元 2011/04/16 I0330 碘苯二乙酸酯 Iodobenzene Diacetate 10G 388元 2011/04/16 I0330 碘苯二乙酸酯 Iodobenzene Diacetate 25G 650元
• 敏感性:Light Sensitive