(2R,5S)-5-Methyl-4,4-diphenyl-1,3,2-dioxathiolane (2R,5S)-5-甲基-4,4-二苯基-1,3,2-二噁硫烷

CAS 126577-49-9 MFCD14636440

化学结构图

126577-49-9
SMILES:

化学属性

Mol. Weight274.33
Melting Point110-113 °C (lit.)
Mol. FormulaC15H14O3S

别名和识别编码

Synonym (2R,5S)-5-甲基-4,4-二苯基-1,3,2-二噁硫烷 (S)-(-)-1,1-二苯基-1,2-丙二醇环亚硫酸酯
MDL NumberMFCD14636440
PubChem Substance ID24862692
CAS Number126577-49-9
Chemical Name(2R,5S)-5-Methyl-4,4-diphenyl-1,3,2-dioxathiolane
Chemical Name Translation(2R,5S)-5-甲基-4,4-二苯基-1,3,2-二噁硫烷
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Organic Sulfates/Sulfites
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Organic Sulfates/Sulfites

相关文献及参考

  • 1. Tetrahedron Lett. 30 , 3659, (1989)
  • Fieser 16 ,160
  • FT-NMR 1 (2), 1593:C / RegBook 1 (2), 2193:F / Structure Index 1 , 344:D:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Organic Sulfates/Sulfites - Organic Building Blocks

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