N,N,N,N-Tetramethyl-1,4-Phenylenediamine N,N,N’,N’-四甲基对苯二胺

CAS 100-22-1 MFCD00008309

化学结构图

100-22-1
SMILES: CN(C)c1ccc(N(C)C)cc1

化学属性

Mol. FormulaC6H4[N(CH3)2]2
Mol. Weight164.25
Boiling Point260 °C(lit.)
Melting Point49-51 °C(lit.)
TSCAYes
Flash Point>;230 °F
Solubilityslightly in cold, more in hot water
Appearance powder

别名和识别编码

Chemical NameN,N,N,N-Tetramethyl-1,4-Phenylenediamine
MDL NumberMFCD00008309
CAS Number100-22-1
Synonym tl85 N,N,N',N'-TETRAMETHYL-1,4-PHENYLENEDIAMINE Wurster's reagent Tetramethyl-p-phenylenediamine N,N,N',N'-Tetramethyl-1,4-Benzenediamine N,N,N',N'-四甲基对苯二胺 N,N,N’,N’-Tetramethyl-benzene-1,4-diamine n,n,n’,n’-tetramethyl-4-benzenediamine Benzene, 1,4-bis(dimethylamino)- 1,4-Bis(dimethylamino)benzene N,N,N’,N’-四甲基对苯二胺 N,N,N',N'-Tetramethyl-p-phenylenediamine TMPD TMPDA TMPPD Wurster 试剂 Wurster蛃 Blue] N,N,N’,N’-四甲基-1,4-苯二胺 TMPDA Wurster 试剂 N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE p-Bis(dimethylamino)benzene TMPD Tetramethyl-p-phenyldiamine TMPPD Wurster's Blue 1,4-BIS(DIMETHYLAMINO)BENZENE 4-Benzenediamine,N,N,N’,N’-tetramethyl-1 N,N,N',N'-Tetramethyl-p-fenylendiamin N,N,N',N'-四甲基-1,4-苯二胺 N,N,N′,N′-四甲基对苯二胺 1,4-bis(dimethylamino)-benzen 四甲基对苯二胺 TL 85 p-Phenylenediamine, N,N,N',N'-tetramethyl- 1,4-Benzenediamine, N,N,N',N'-tetramethyl- N,N,N’,N’-Tetramethyl-p-phenyl WURSTER'S REAGENT N,N,N',N'-四甲基对苯二胺, 98+% n,n,n’,n’-tetramethyl-p-phenylenediamin n,n,n’,n’-tetramethyl-p-fenylendiamin
EC Number202-831-6
Beilstein Registry Number1564025
PubChem Substance ID7490
Merck Number14,9228
Chemical Name TranslationN,N,N’,N’-四甲基对苯二胺
Wiswesser Line Notation1N1&R DN1&1
LabNetwork Molecule IDLN00198017
InChIInChI=1S/C10H16N2/c1-11(2)9-5-7-10(8-6-9)12(3)4/h5-8H,1-4H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines

相关文献及参考

  • Electron acceptor in studies of catalytic properties of oxoreductases in cellular organelles: Anal. Biochem., 131, 404 (1983). Reducing agent for cytochrome c.
  • Compare N,N-Dimethyl-p-phenyl­enediamine dihydrochloride, A10343.
  • Powerful electron donor which readily forms stable, dark blue radical cation: J. Am. Chem. Soc., 61, 1981 (1939); 65, 1747 (1943), which is involved in a wide variety of redox reactions:

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSST4200000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Safety Statements
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
Packing GroupIII
UN Number UN 2811 6.1/PG 3 UN1673
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Air & Light Sensitive Refrigerator (+4°C)
Hazard Codes Xn
Hazard Class6.1(a) 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 90,260,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 42 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 780 mg/m3/10M
TOXIC EFFECTS :
   Behavioral - irritability
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,DEC1942

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 23700 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 10 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

其他信息

  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • Sigma Aldrich:100-22-1(sigmaaldrich)
  • 急性毒性:口服-大鼠 LDL0: 500 毫克/公斤; 口服-野鸟 LD50: 23.7 毫克/公斤
  • 毒性分级:高毒
  • N,N,N',N'-四甲基对苯二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 170790050 N,N,N',N'-四甲基对苯二胺 N,N,N',N'-Tetramethyl-p-phenylenediamine 98% 5 GR 901元 2010/06/21 170790250 N,N,N',N'-四甲基对苯二胺 N,N,N',N'-Tetramethyl-p-phenylenediamine 98% 25 GR 3003元 2010/05/25 L00559 N,N,N',N'-四甲基对苯二胺, 98+% N,N,N',N'-Tetramethyl-p-phenylenediamine, 98+% 50g 1554元
  • Alfa Aesar:N,N,N',N'-四甲基对苯二胺,98+% N,N,N',N'-Tetramethyl-p-phenylenediamine, 98+%(100-22-1)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • F:10
  • color:off-white to gray
  • Acros Organics:N,N,N',N'-四甲基对苯二胺 N,N,N',N'-Tetramethyl-p-phenylenediamine, 98%(100-22-1)
  • 用途一:用作固化剂
  • MOL 文件:100-22-1.mol
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes

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