Methyltriphenylphosphonium chloride 三苯基甲基氯化鏻

CAS 1031-15-8 MFCD00797851

化学结构图

1031-15-8
SMILES: C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]

化学属性

Mol. FormulaCH3P(C6H5)3Cl
Mol. Weight313
Melting Point221.0 to 225.0 deg-C
TSCANo

别名和识别编码

Chemical NameMethyltriphenylphosphonium chloride
MDL NumberMFCD00797851
PubChem Substance ID354333154
CAS Number1031-15-8
EC Number418-400-2
Synonym Methyltriphenylphosphoniumchlorid Methyltriphenylphosphonium chloride METHYL-TPP-CHLORID Methyl-triphenyl-phosphonium chloride Methyltriphenylphosphonyl chloride MTPP-CHLORID Phosphorane, chloromethyltriphenyl- Chloromethyltriphenylphosphorane 甲基三苯基氯化膦 Triphenylmethylchlorophosphine 三苯基甲基氯化膦 METHYLTRIPHENYLPHOSPHONIUM CHLORIDE PHOSPHONIUM,METHYLTRIPHENYL-,CHLORIDE
Chemical Name Translation三苯基甲基氯化鏻
LabNetwork Molecule IDLN00201587
Reaxys-RN4168881
InChIInChI=1S/C19H18P.ClH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Catalysts for Polymerization, Chemical Synthesis, Materials Science, Olefination, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization, Synthetic Reagents, Wittig Reagents
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic
  • {SNA} C-C Bond Formation, Catalysts for Polymerization, Chemical Synthesis, Olefination, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization, Synthetic Reagents, Wittig Reagents, 材料科学

相关文献及参考

  • 1. K. Sakakibara, et al., Chem. Commun. 31 , 3334-3336, (2006)
  • 2. K. F. Khaled, Appl. Surf. Sci. 230 , 307-318, (2004)
  • 3. D. Rideout, et al., Int. J. Cancer 57 , 247-253, (1994)
  • 4. J. D. White and J. D. Hansen, J. Am. Chem. Soc. 124 , 4950-4951, (2002)
  • Short: ELINCS Title: Sixth publication of Elincs (according to Article 21 of Directive 67/548/EEC) Page: 1-131 Year: 2003 Keyword: European List of Notified Chemical Substances Internet Resource: http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CELEX:52003DC0642:EN:NOT Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=eli
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P312+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P310
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Hazard Codes Xn;N Xn,N Xn;N,N,Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S22 Do not breathe dust 不要吸入粉尘；
UN Number 3077 UN 3077 UN3077
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R38 Irritating to skin 刺激皮肤
  • R51/53
Storage condition Hygroscopic
Packing GroupIII
Hazard Class9

其他信息

  • Sigma Aldrich:1031-15-8(sigmaaldrich)
  • MOL 文件:1031-15-8.mol
  • 用途一:医药中间体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination

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