N1,N1,N4,N4-Tetramethylbutane-1,4-diamine N,N,N,N-四甲基-1,4-丁二胺

CAS 111-51-3 MFCD00008338

化学结构图

111-51-3
SMILES: CN(C)CCCCN(C)C

化学属性

Mol. FormulaC8H20N2
Mol. Weight144.26
Refractive index1.4270 to 1.4300
Boiling Point166-167 °C at 760 mmHg
Density0.792 g/mL at 25 °C(lit.)
Flash Point46°C(lit.)
Melting Point-100 °C

别名和识别编码

Chemical NameN1,N1,N4,N4-Tetramethylbutane-1,4-diamine
MDL NumberMFCD00008338
CAS Number111-51-3
Synonym N,N,N',N'-Tetramethylputrescine {LY} N,N,N',N'-Tetramethylputrescine {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N'-Tetramethylputrescine
PubChem Substance ID87577060
EC Number203-878-5
Beilstein Registry Number4(4)1284
Reaxys-RN1735538
Merck Number9226
Chemical Name TranslationN,N,N,N-四甲基-1,4-丁二胺
LabNetwork Molecule IDLN01363387
Canonical SMILESCN(C)CCCCN(C)C
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分类

  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Tertiary Amines
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Amine Monomers, Monomers, Polymer Science, Tertiary Amines, 材料科学

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Merck 14 ,9226
  • Beil. 4 ,IV,1284
  • Aldrich MSDS 1 , 1679:C / Corp MSDS 1 (2), 3292:C / FT-IR 2 (1), 483:B / FT-IR 1 (1), 307:A / FT-NMR 1 (1), 498:A / IR-Spectra (2), 161:H / IR-Spectra (3), 179:B / NMR-Reference 2 (1), 265:A / RegBook 1 (1), 329:H / Structure Index 1 , 45:D:5 / Vapor Phase 3 , 394:D

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
RTECSEJ7530000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340
Signal word Danger {} {} {} {TCI}
UN Number UN 2734 8/PG 2 2734
Packing GroupII
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R10 Flammable 易燃
Hazard Class8/3
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Flammables area {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : >316 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

其他信息

  • TCI Shanghai:N,N,N',N'-四甲基-1,4-丁二胺 N,N,N',N'-Tetramethyl-1,4-diaminobutane,>;98.0%(GC)(T)(111-51-3)
  • N,N,N',N' - 四甲基-1,4-丁二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1289 N,N,N',N'-四甲基-1,4-丁二胺 N,N,N',N'-Tetramethyl-1,4-diaminobutane 25ML 1240元 2010/06/21 155600250 N,N,N',N' - 四甲基-1,4-丁二胺 N,N,N',N'-Tetramethyl-1,4-butanediamine 97% 25 GR 1983元 2010/06/21 155600050 N,N,N',N' - 四甲基-1,4-丁二胺 N,N,N',N'-Tetramethyl-1,4-butanediamine 97% 5 GR 602元
  • 图谱信息:N,N,N',N' - 四甲基-1,4-丁二胺(111-51-3)核磁图( 13 CNMR) N,N,N',N' - 四甲基-1,4-丁二胺(111-51-3)红外图谱(IR1) N,N,N',N' - 四甲基-1,4-丁二胺(111-51-3)质谱(MS) N,N,N',N' - 四甲基-1,4-丁二胺(111-51-3)核磁图( 1 HNMR)
  • Sigma Aldrich:111-51-3(sigmaaldrich)
  • Acros Organics:N,N,N',N'-四甲基-1,4-丁二胺 N,N,N',N'-Tetramethyl-1,4-butanediamine, 97%(111-51-3)
  • MOL 文件:111-51-3.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Amine Monomers - Monomers
  5. Tertiary Amines - Amine Monomers

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