3,3'-Thiodipropionitrile 硫代丙二腈

CAS 111-97-7 MFCD00013829

化学结构图

111-97-7
SMILES: N#CCCSCCC#N

化学属性

Mol. FormulaC6H8N2S
Mol. Weight140.21
Refractive indexn20/D 1.499(lit.)
Boiling Point191-194 °C/7 mmHg(lit.)
Density1.11 g/mL at 25 °C(lit.)
Melting Point24-25 °C(lit.)
Flash Point195 °C

别名和识别编码

Chemical Name3,3'-Thiodipropionitrile
MDL NumberMFCD00013829
CAS Number111-97-7
Synonym .beta.,.beta.’-Thiodipropionitrile 2,2'-Thiodiethylkyanid 2,2’-thiodiethylkyanid 2-CYANOETHYL THIOETHER 2-Cyanoethyl sulfide 2-Cyanoethyl thioether 2-cyanoethyl sulfide 2-cyanoethylsulfide 3,3'-Thiobispropannitril 3,3'-Thiodipropionitrile 3,3'-Thiodipropionsäurenitril 3,3'-sulfanediyl-bis-propionitrile 3,3'-thiobispropanenitrile 3,3'-thiodipropiononitrile 3,3'-THIODIPROPIONITRILE 3,3'-Thiodipropionitrile {} {} {} {} {} {} {Chemicalbook} BETA-CYANOETHYL THIO ETH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} BETA,BETA'-DICYANOETHYL THIOETHER {} {} {} {} {} {} {} {} {Chemicalbook} 3,3’-硫代二丙腈 {} {} {} {} {} {} {} {} {} {Chemicalbook} 3,3’-thiodi-propionitril {} {} {} {} {} {} {} {} {} {} {Chemi
PubChem Substance ID8151
EC Number203-926-5
Beilstein Registry Number1701139
Chemical Name Translation硫代丙二腈
Wiswesser Line NotationNC2S2CN
InChIInChI=1S/C6H8N2S/c7-3-1-5-9-6-2-4-8/h1-2,5-6H2
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分类

  • {uni_hamburg} no charge; sulfide; 1fragment
  • {SNA} Building Blocks, C6 to C7, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUG4375000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 4500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4210 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

Storage condition No Data Available

其他信息

  • 图谱信息:硫代丙二腈(111-97-7)红外图谱(IR1) 硫代丙二腈(111-97-7)红外图谱(IR2) 硫代丙二腈(111-97-7)核磁图( 1 HNMR) 硫代丙二腈(111-97-7)红外图谱(IR3) 硫代丙二腈(111-97-7)质谱(MS) 硫代丙二腈(111-97-7)核磁图( 13 CNMR)
  • 硫代丙二腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0207 3,3'-硫代二丙腈 3,3'-Thiodipropionitrile 25G 319元 2010/06/21 331380050 硫代丙二腈 3,3'-Thiodipropionitrile 98% 5 GR 464元
  • 急性毒性:口服-大鼠 LD50: 4210 毫克/ 公斤
  • 灭火剂:雾状水、泡沫、干粉、二氧化碳、砂土
  • 毒性分级:中毒
  • 刺激数据:皮肤-兔子 500 毫克/24小时 轻度; 眼睛-兔子 500 毫克/24小时 轻度
  • TCI Shanghai:3,3'-硫代二丙腈 3,3'-Thiodipropionitrile,>;98.0%(GC)(111-97-7)
  • Sigma Aldrich:111-97-7(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与食品、氧化剂、酸类分开储运
  • 可燃性危险特性:明火可燃; 受热放出剧毒含腈气体
  • MOL 文件:111-97-7.mol
  • 类别:有毒物品
  • Acros Organics:硫代丙二腈 3,3'-Thiodipropionitrile(111-97-7)
  • F:13

系列性分类


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