Bis(2-methoxyethyl) phthalate 邻苯二甲酸二甲氧基乙酯

CAS 117-82-8 MFCD00042842

化学结构图

117-82-8
SMILES: COCCOC(=O)c1ccccc1C(=O)OCCOC

化学属性

Mol. FormulaC14H18O6
Mol. Weight282.29
Refractive index1.5020 to 1.5040
Boiling Point230°C at 760 mmHg
Density1.173 g/mL at 20 °C(lit.)
Flash Point121°C
TSCAYes
Appearance 浅黄色油状液体。凝固点-40℃,沸点350℃,相对密度1.170-1.176(15.5/15.5℃)。能与醇、丙酮、石油醚和油类等多种有机溶剂混溶,微溶于甘油、乙二醇。20℃时在水中溶解度为3.4%,具芳香气味。
Melting Point-42.4 °C

别名和识别编码

Chemical NameBis(2-methoxyethyl) phthalate
Synonym Bis(2-methoxyethyl) phthalate {LY} Bis(2-methoxyethyl) phthalate {} {LY} Bis(2-methoxyethyl) phthalate {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-methoxyethyl) phthalate {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00042842
CAS Number117-82-8
PubChem Substance ID87575080
EC Number204-212-6
Beilstein Registry Number9(2)597
Chemical Name Translation邻苯二甲酸二甲氧基乙酯
Reaxys-RN2056929
Wiswesser Line Notation1O2OVR BVO2O1
LabNetwork Molecule IDLN00221439
InChIInChI=1S/C14H18O6/c1-17-7-9-19-13(15)11-5-3-4-6-12(11)14(16)20-10-8-18-2/h3-6H,7-10H2,1-2H3
Canonical SMILESO=C(OCCOC)C1=CC=CC=C1C(OCCOC)=O
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分类

  • {SNA} Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ester; ether; 1fragment
  • {SNA} A-B, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Aromatics, B, BI - BZ, Chemical Class, Chromatography, Environmental Standards, Esters, Food & Beverage Standards, Food Residuals, Phthalates, Plasticizer, Plasticizers, Standards for Personal Care and Cosmetic Products, Volatiles/

产品应用

  • 主要用作乙酸纤维素的增塑剂,它的挥发性比邻苯二甲酸二乙酯小,可有很好的耐久性,同时使薄膜具有坚韧性。可用于漆包线、电影胶片、高强度清漆、胶粘剂和层压板胶粘剂等;也用作气相色谱固定液、三乙酸片基的增感剂和溶剂。

相关文献及参考

  • Short: IV/18B
  • Short: EINECS
  • Beilstein:9(2)597

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTI1400000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P308+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Risk Statements
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Hazard Codes T
Packing GroupIII
UN Number
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3736 uL/kg
TOXIC

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2510 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,691,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : >20 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0391-1170

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14CYAT "Industrial Hygiene and Toxicology," 2nd ed., Patty, F.A., ed., New
   York, John Wiley & Sons, Inc., 1958-63  Volume(issue)/page/year: 2,1904,1963

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1595 ppm/6H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
REFERENCE :
   14CYAT "Industrial

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 1500 mg/kg
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   53,71,1983

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1190 mg/kg
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   29,35,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 374 mg/kg
SEX/DURATION            : female 5-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 61,51,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 2380 ug/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   29,35,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 2380 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Alfa Aesar:邻苯二甲酸二(2-甲氧基乙基)酯,96% Bis(2-methoxyethyl) phthalate, 96%(117-82-8)
  • 邻苯二甲酸二甲氧乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0965 邻苯二甲酸双(2-甲氧基乙基)酯 Bis(2-methoxyethyl) Phthalate 500G 728元 2014/06/02 P0965 邻苯二甲酸双(2-甲氧基乙基)酯 Bis(2-methoxyethyl) Phthalate 25G 168元 2010/05/25 44089 邻苯二甲酸二(2-甲氧基乙基)酯,96% Bis(2-methoxyethyl) phthalate, 96% 50g 210元
  • TCI Shanghai:邻苯二甲酸二(2-甲氧基乙基)酯;增塑剂DOP Phthalic Acid Bis(2-methoxyethyl) Ester,>;96.0%(GC)(117-82-8)
  • MSDS 信息:Bis(2-methoxyethyl) phthalate(117-82-8).msds
  • Sigma Aldrich:117-82-8(sigmaaldrich)
  • 用途二:该品可与乙酸纤维素、硝基纤维素、乙基纤维素、乙烯基树脂、聚乙烯醇缩丁醛、醇酸树脂等相容。主要用作乙酸纤维素的增塑剂,它的挥发性比邻苯二甲酸二乙酯小,可有很好的耐久性,同时使薄膜具有坚韧性。可用于漆包线、电影胶片、高强度清漆、胶粘剂和层压板胶粘剂等;也用作气相色谱固定液、三乙酸片基的增感剂和溶剂。
  • 上游原料:乙二醇甲醚
  • 能与醇、丙酮、石油醚和油类等多种有机溶剂混溶,微溶于甘油、乙二醇。具芳香气味。
  • 用途三:主要用作乙酸纤维素的增塑剂,它的挥发性比邻苯二甲酸二乙酯小,可有很好的耐久性,同时使薄膜具有坚韧性。可用于漆包线、电影胶片、高强度清漆、胶粘剂和层压板胶粘剂等;也用作气相色谱固定液、三乙酸片基的增感剂和溶剂。
  • 方法一:由环氧乙烷与甲醇、三氟化硼乙醚进行加成反应,中和反应产物得甲氧基乙醇。再与苯酐进行酯化反应,然后用活性炭脱色、蒸馏、水洗、碱洗、脱水、压滤而得成品。酯化反应产物水洗后,进行减压蒸馏,这种后处理工艺也被工业生产采用。工业品DMEP的含量≥99。原料消耗定额:苯酐750kg/t、环氧乙烷820kg/t、甲醇660kg/t。
  • MOL 文件:117-82-8.mol
  • 用途一:用作醋酸纤维素的增塑剂
  • 图谱信息:邻苯二甲酸二甲氧乙酯(117-82-8)Raman光谱 邻苯二甲酸二甲氧乙酯(117-82-8)核磁图( 1 HNMR) 邻苯二甲酸二甲氧乙酯(117-82-8)核磁图( 13 CNMR) 邻苯二甲酸二甲氧乙酯(117-82-8)质谱(MS) 邻苯二甲酸二甲氧乙酯(117-82-8)红外图谱(IR1)

系列性分类


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