Cyclopropanecarboxaldehyde 环丙烷甲醛

CAS 1489-69-6 MFCD00012261

化学结构图

1489-69-6
SMILES: O=CC1CC1

化学属性

Mol. FormulaC4H6O
Mol. Weight70.09
Density0.938 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.4298(lit.)
Boiling Point99.5°C at 760 mmHg
Flash Point7°C
TSCAYes
Stability对空气敏感

别名和识别编码

Chemical NameCyclopropanecarboxaldehyde
Synonym Cyclopropanecarbaldehyde {LY} Cyclopropanecarbaldehyde {} {LY} Cyclopropanecarbaldehyde {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00012261
CAS Number1489-69-6
EC Number000-000-0
Beilstein Registry Number906781
PubChem Substance ID123114
Alfabeta NameCYCLOPROPANECARBALDEHYDE
Chemical Name Translation环丙烷甲醛
InChIKeyJMYVMOUINOAAPA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007968
InChIInChI=1S/C4H6O/c5-3-4-1-2-4/h3-4H,1-2H2
Canonical SMILESO=CC1CC1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; carbocycle; alicycle; 3ring; aldehyde; 1fragment
  • {SNA} Aldehydes, Building Blocks, C1 to C6, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

产品应用

  • 用于制备环化四丙基四氢萘酮,需经过对映体选择性的钯催化的环加成反应。也是合成中引入环丙基的常用试剂。

相关文献及参考

  • Short: II/25C
  • Beilstein:7(4)4
  • Short: II/6
  • Reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides: Synth. Commun., 25, 3351 (1995):
  • Short: III/38B

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSGZ1005000
Packing GroupII
UN Number UN2924 2924 UN 2924 3/PG 2
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen Air Sensitive Refrigerator {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nit
Hazard Codes F,C F;C
Warnings IRRITANT
Hazard Class3

其他信息

  • 环丙甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 c1707 环丙甲醛 Cyclopropanecarboxaldehyde 5G 973元 2014/06/02 c1707 环丙甲醛 Cyclopropanecarboxaldehyde 1G 320元 2010/06/21 366820050 环丙甲醛 Cyclopropanecarboxaldehyde 98% 5 GR 1398元
  • 下游产品:1-(环丙甲基)哌嗪 --> N-Boc-4-(环丙甲基)哌嗪
  • Sigma Aldrich:1489-69-6(sigmaaldrich)
  • 检测方法:GC
  • 敏感性:Air Sensitive
  • 用途一:用于制备环化四丙基四氢萘酮,需经过对映体选择性的钯催化的环加成反应。也是合成中引入环丙基的常用试剂。
  • MSDS 信息:Cyclopropanecarboxaldehyde(1489-69-6).msds
  • MOL 文件:1489-69-6.mol
  • Acros Organics:环丙烷甲醛 Cyclopropanecarboxaldehyde, 98%(1489-69-6)
  • 存储注意事项:氮气保护
  • 上游原料:二氯甲烷 --> 硫酸镁 --> 三乙胺 --> 次氯酸钠 --> 草酰氯 --> 磷酸二氢钾 --> 溴化钾 --> 氯铬酸吡啶盐 --> 2,2,6,6-四甲基哌啶氧化物 --> 羟甲基环丙烷 --> 溴代环丙烷
  • Alfa Aesar:环丙甲醛,98% Cyclopropanecarboxaldehyde, 98%(1489-69-6)
  • TCI Shanghai:环丙甲醛 Cyclopropanecarboxaldehyde,>;97.0%(GC)(1489-69-6)

系列性分类