2,4-Dinitrophenyl thiocyanate 硫氰酸2,4-二硝基苯酯

CAS 1594-56-5 MFCD00047702

化学结构图

1594-56-5
SMILES: N#CSc1ccc([N+](=O)[O-])cc1[N+](=O)[O-]

化学属性

Mol. FormulaC7H3N3O4S
Mol. Weight225.18
Melting Point138-140 °C
TSCANo
Solubility不溶于水,微溶于甲醇、甲苯、氯仿等。

别名和识别编码

Chemical Name2,4-Dinitrophenyl Thiocyanate
MDL NumberMFCD00047702
CAS Number1594-56-5
Synonym 2,4-Dinitro-1-thiocyanatobenzene {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dinitro-1-thiocyanatobenzene {} {} {} {}
EC Number216-477-5
Beilstein Registry Number1983292
Reaxys-RN1983292
PubChem Substance ID15325
Chemical Name Translation硫氰酸2,4-二硝基苯酯
Wiswesser Line NotationWNR CNW DSCN
LabNetwork Molecule IDLN01746412
InChIInChI=1S/C7H3N3O4S/c8-4-15-7-2-1-5(9(11)12)3-6(7)10(13)14/h1-3H
Canonical SMILESC1=CC(=C(C=C1[N+](=O)[O-])[N+](=O)[O-])SC#N
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相关文献及参考

  • Reagent for Ag.

安全信息

RTECSXK9450000
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition Moisture Sensitive
Packing GroupIII
UN Number 2811
Signal word
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H228 Flammable solid 易燃固体
  • H301+H311+H331
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
Hazard Class6.1
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 51 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCBPBS Pesticide Biochemistry and Physiology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1971-  Volume(issue)/page/year:
   2,95,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1650 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,62,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        :

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,259,1971

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,34,1953

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 25 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 3 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,19,1976

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 30 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 131,101,1984

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 10 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 78,177,1980

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 图谱信息:二硝散(1594-56-5)红外图谱(IR2) 二硝散(1594-56-5)核磁图( 1 HNMR) 二硝散(1594-56-5)红外图谱(IR3) 二硝散(1594-56-5)红外图谱(IR1) 二硝散(1594-56-5)质谱(MS)
  • 类别:农药
  • MSDS 信息:2,4-二硝基硫氰基苯(1594-56-5).msds
  • 毒性分级:中毒
  • 外观性质:黄色无臭结晶。
  • 二硝散价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0199 硫氰酸2,4-二硝基苯酯 2,4-Dinitrophenyl Thiocyanate 25G 1020元 2014/06/02 T0199 硫氰酸2,4-二硝基苯酯 2,4-Dinitrophenyl Thiocyanate 1G 150元 2010/05/25 B24147 2,4-二硝基硫氰酸苯酯, 98% 2,4-Dinitrophenyl thiocyanate, 98% 25g 1092元
  • 急性毒性:口服- 小鼠 LD50: 2750 毫克/ 公斤
  • TCI Shanghai:2,4-二硝基硫氰酸苯酯 2,4-Dinitrophenyl Thiocyanate,>;98.0%(GC)(1594-56-5)
  • Alfa Aesar:2,4-二硝基硫氰酸苯酯,98% 2,4-Dinitrophenyl thiocyanate, 98%(1594-56-5)
  • 可燃性危险特性:燃烧产生有毒硫氧化物和氮氧化物气体
  • 灭火剂:干粉、泡沫、砂土
  • 敏感性:Moisture Sensitive
  • MOL 文件:1594-56-5.mol

系列性分类


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