4-Chlorocinnamic acid, 99% 4-氯肉桂酸

CAS 1615-02-7 MFCD00004396

化学结构图

1615-02-7
SMILES: O=C(O)/C=C/c1ccc(Cl)cc1

化学属性

Mol. FormulaC9H7ClO2
Mol. Weight182.60
Melting Point248-250°C
Density1.332
TSCANo
Appearance 无色结晶。有顺式和反式两种。溶于乙醇,顺式熔点110.5℃,反式熔点249-250℃。
Boiling Point325.3°C at 760 mmHg

别名和识别编码

Chemical Name4-Chlorocinnamic acid, 99%
CAS Number1615-02-7
Alfabeta NameCHLOROCINNAMICACID 4-
MDL NumberMFCD00004396
Synonym 4-Chlorocinnamic acid {LY} 4-Chlorocinnamic acid {} {LY} 4-Chlorocinnamic acid {} {} {LY} 4-Chlorocinnamic acid {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorocinnamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number2044025
PubChem Substance ID24892589
EC Number216-564-8
Reaxys-RN2044025
Chemical Name Translation4-氯肉桂酸
InChIKeyGXLIFJYFGMHYDY-ZZXKWVIFSA-N
Wiswesser Line NotationQV1U1R DG
LabNetwork Molecule IDLN00224378
Canonical SMILESO=C(O)/C=C/C1=CC=C(Cl)C=C1
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信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • Building Blocks, C9, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carboxylic acid; 1fragment
  • {SA} Building Blocks, C9, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {SNA} Building Blocks, C9, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks

产品应用

  • 有机合成中间体,用于合成对氯苯丙酸,生产除草剂麦敌散。

相关文献及参考

  • Beilstein:9,594
  • Short: EINECS
  • Short: III/20b

安全信息

WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn Xn,Xi
RTECSGD8490000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1622 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHARAT Pharmazie.  (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18,
   Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1946-  Volume(issue)/page/year:
   23,714,1968

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >350 mg/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
   Behavioral - ataxia
   Behavioral - rigidity (including catalepsy)
REFERENCE :
   IJSIDW Indian Journal of Pharmaceutical Sciences.  (Kalina, Santa Cruz
   (East), Bombay 400 029, India)  V.40(2)-    1978-  Volume(issue)/page/year:
   49,77,1987

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Acros Organics:4-氯肉桂酸 4-Chlorocinnamic acid, predominantly trans, 99%(1615-02-7)
  • 4-氯肉桂酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0149 4-氯肉桂酸 4-Chlorocinnamic Acid 500G 5170元 2014/06/02 C0149 4-氯肉桂酸 4-Chlorocinnamic Acid 25G 610元 2010/06/21 108940250 4-氯肉桂酸 4-Chlorocinnamic acid 99%, predominantly trans 25 GR 656元
  • 下游产品:3-(4-氯苯基)丙酸
  • Alfa Aesar:4-氯苯乙烯酸,99% 4-Chlorocinnamic acid, predominantly trans, 99%(1615-02-7)
  • MSDS 信息:4-Chlorocinnamic acid(1615-02-7).msds
  • 上游原料:4-氯苯甲醛 --> 稀硫酸
  • 用途三:有机合成中间体,用于合成对氯苯丙酸,生产除草剂麦敌散。
  • Hazard Note:Irritant
  • TCI Shanghai:4-氯肉桂酸 4-Chlorocinnamic Acid,>;98.0%(T)(1615-02-7)
  • Sigma Aldrich:1615-02-7(sigmaaldrich)
  • 方法一:由对氯苯甲醛与乙酐反应而得。将对氯苯甲醛、乙酐和乙酸钠在一起在180℃下反应13h。反应毕,稍冷,倒入水中,过滤,用水洗涤滤饼,用氨水反复溶解,至仅残留少量棕黄色粘稠状物为止。将所得铵盐溶液过滤,用3N稀硫酸将对氯肉桂酸重新析出,经过滤干燥得产品。产率约为80%。
  • 用途二:有机合成中间体,用于合成对氯苯丙酸,生产除草剂麦敌散。
  • MOL 文件:1615-02-7.mol
  • 用途一:用于合成除草剂
  • 检测方法:HPLC,NMR

系列性分类


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