4-Amino-3-nitropyridine 4-氨基-3-硝基吡啶

CAS 1681-37-4 MFCD00160304

化学结构图

1681-37-4
SMILES: Nc1ccncc1[N+](=O)[O-]

化学属性

Mol. FormulaC5H5N3O2
Mol. Weight139.11
Density1.422
Melting Point203-207°C
TSCANo
Boiling Point350.4°C at 760 mmHg

别名和识别编码

Chemical Name4-Amino-3-nitropyridine
CAS Number1681-37-4
Alfabeta NameAMINONITROPYRIDINE 43---
MDL NumberMFCD00160304
Synonym 4-Amino-3-nitropyridine {LY} 4-Amino-3-nitropyridine {} {LY} 4-Amino-3-nitropyridine {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-nitropyridine {} {} {} {} {} {} {} {}
EC Number000-000-0
Beilstein Registry Number383710
PubChem Substance ID548803
Chemical Name Translation4-氨基-3-硝基吡啶
Reaxys-RN383710
LabNetwork Molecule IDLN00009518
InChIInChI=1S/C5H5N3O2/c6-4-1-2-7-3-5(4)8(9)10/h1-3H,(H2,6,7)
Canonical SMILESNC1=C([N+]([O-])=O)C=NC=C1
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分类

  • {SNA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes Xn
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Alfa Aesar:4-氨基-3-硝基吡啶,96% 4-Amino-3-nitropyridine, 96%(1681-37-4)
  • 4-氨基-3-硝基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A2260 4-氨基-3-硝基吡啶 4-Amino-3-nitropyridine 25G 3080元 2014/06/02 A2260 4-氨基-3-硝基吡啶 4-Amino-3-nitropyridine 5G 904元 2010/06/21 360630010 4-氨基-3-硝基吡啶 4-Amino-3-nitropyridine 98% 1 GR 783元
  • MOL 文件:1681-37-4.mol
  • 下游产品:3-氨基-4-乙酰氨基吡啶 --> 3,4-二氨基吡啶 --> 2-甲基咪唑[4,5-C]吡啶 --> 3,4-二氨基-6-氯吡啶 --> 4-乙酰氨基-3-硝基吡啶
  • Sigma Aldrich:1681-37-4(sigmaaldrich)
  • Acros Organics:4-Amino-3-nitropyridine, 98%(1681-37-4)
  • 检测方法:HPLC

系列性分类

  1. C8 to C9 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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