2-Iodothiophene 2-碘噻吩

CAS 3437-95-4 MFCD00005424

化学结构图

3437-95-4
SMILES: Ic1cccs1

化学属性

Mol. FormulaC4H3IS
Mol. Weight210.04
Boiling Point73 °C at 15 mmHg
Melting Point-40°C
TSCAT
Refractive index1.6500 to 1.6540
Density1.902
Flash Point77°C
pH:A

别名和识别编码

Chemical Name2-Iodothiophene
CAS Number3437-95-4
Alfabeta NameIODOTHIOPHENE 2-
MDL NumberMFCD00005424
PubChem Substance ID18921
EC Number222-342-1
Beilstein Registry Number104666
Synonym 2-Iodothiophene {LY} 2-Iodothiophene {} {LY} 2-Iodothiophene {} {} {LY} 2-Iodothiophene {} {} {} {LY} 2-Iodothiophene {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodo
Chemical Name Translation2-碘噻吩
Reaxys-RN104666
InChIKeyROIMNSWDOJCBFR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116731
InChIInChI=1S/C4H3IS/c5-4-2-1-3-6-4/h1-3H
Canonical SMILESIC1=CC=CS1
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分类

  • Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiophenes
  • {SNA} Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiophenes

相关文献及参考

  • Beil. 17 ,V,1,309
  • Aldrich MSDS 1 , 1103:D / Corp MSDS 1 (1), 2008:C / FT-IR 1 (2), 593:B / FT-IR 2 (3), 3469:B / FT-NMR 1 (3), 45:B / IR-Spectra (3), 1207:E / NMR-Reference 2 (2), 468:B / RegBook 1 (2), 2331:K / Structure Index 1 , 367:A:3 / Vapor Phase 3 , 1468:C
  • In contrast to 2-Bromothiophene, A11959 which requires a copper catalyst, reaction with a variety of thiols, including Thiophene-2-thiol, B22642 to give 2,2'-dithienyl sulfide, proceeds in high yield in the absence of catalyst, base or solvent: Tetrahedron Lett., 36, 8439 (1995).

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition -20°C, protect from light {LY} -20°C, protect from light Light Sensitive {} {LY} -20°C, protect from light {} {} {LY} -20°C, protect from light {} {} {} {LY} -20°C, protect from light {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect fro
UN Number 1993
Packing GroupIII

系列性分类


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