1-Chloro-4-Fluorobenzene 1-氯-4-氟苯

CAS 352-33-0 MFCD00000603

化学结构图

352-33-0
SMILES: Fc1ccc(Cl)cc1

化学属性

Mol. FormulaC6H4ClF
Mol. Weight131
Boiling Point129-130
TSCAT
Refractive index1.4940 to 1.4960
Density1.226
Melting Point-27 - -26
Flash Point29°C(lit.)
Solubility不溶于水，溶于醇、醚、苯。

别名和识别编码

Chemical Name1-Chloro-4-Fluorobenzene
CAS Number352-33-0
Alfabeta NameCHLOROFLUOROBENZENE 14---
MDL NumberMFCD00000603
PubChem Substance ID9604
EC Number206-521-1
Beilstein Registry Number1904542
Reaxys-RN1904542
Synonym {uni_hamburg} 1-chloro-4-fluorobenzene solution 4-Fluorochlorobenzene p-Monofluoromonochlorobenzene 4-Fluorophenyl chloride 4-chlorofluorobenzene 4-CHLOROFLUOROBENZENE 1,4-Fluorochlorobenzene p-Fluorochlorobenzene 4-CHLOROFLUOROBENZENE 99% (GC) 4-FLUOROCHLOROBENZENE 對氯氟苯 4-Chlorofluorobenzene 1-Chloro-4-fluorobenzene,98% p-Monofluoromonochlorobenzene 1-Chloro-4-fluorobenzene 4-氯氟苯 4-Chlor-fluorbenzol 1-chloro-4-fluoro-benzen 4-氯氟苯;4-氟氯苯;对氯氟苯;对氟氯苯 1-chloro-4-fluoro-benzene P-CHLOROFLUOROBENZENE Benzene, 1-chloro-4-fluoro- 对氟氯苯 1-CHLORO-4-FLUOROBENZENE, 1000MG, NEAT 4-氟氯苯 1-Chloro-4-fluorobenzene99% 1-氯-4-氟苯 1-氯-4-氟苯,98% 4-Chlorfluorbenzol p-Chlorofluorobenzene 对氯氟苯 4-Fluorchlorbenzol P-FLUOROCHLOROBENZENE 1-Fluoro-4-chlorobenzene 1-CHLORO-4-FLUOROBENZENE, 1X1ML, MEOH, 5 000UG/ML
Chemical Name Translation1-氯-4-氟苯
InChIKeyRJCGZNCCVKIBHO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225279
InChIInChI=1S/C6H4ClF/c7-5-1-3-6(8)4-2-5/h1-4H
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分类

  • Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, C, CH, Chemical Class, Chromatography, EPA, Environmental Standards, Fluoro, Gasoline Range organics (GRO), Gasoline, Diesel, Petroleum, Halogenated, Method Specific, UST/GRO/DRO, Volatiles/ Semivolatiles
  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks,

相关文献及参考

  • Short: II/27B
  • Lithiation with LDA occurs mainly ortho to F; subsequent carboxylation gives 5-chloro-2-fluorobenzoic acid in moderate yield: Tetrahedron Lett., 33, 7495 (1992). The selectivity is improved by the use of the superbasic combination of n-BuLi and KO-t-Bu, and the yield is increased to 86%: Tetrahedron Lett., 37, 6551 (1996).

安全信息

Warnings 危化品目录(2015) IRRITANT, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H370 Causes damage to organs 导致器官损伤
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P303+P361+
  • P303+P361+P353
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1993
Packing GroupIII
Hazard Class3
Storage condition Flammables area
Restrict 危险品

其他信息

  • 外观性质:无色或浅黄色液体。
  • Sigma Aldrich:352-33-0(sigmaaldrich)
  • Hazard Note:Flammable/Irritant
  • TSCA:T
  • MSDS 信息:对氯氟苯(352-33-0).msds
  • TCI Shanghai:1-氯-4-氟苯 4-Chlorofluorobenzene,>;95.0%(GC)(352-33-0)
  • Acros Organics:对氯氟苯 1-Chloro-4-fluorobenzene, 98%(352-33-0)
  • 1-氯-4-氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0659 4-氯氟苯 1-Chloro-4-fluorobenzene 25G 411元 2014/06/02 C0659 4-氯氟苯 1-Chloro-4-fluorobenzene 250G 2140元 2010/06/21 208200050 1-氯-4-氟苯 1-Chloro-4-fluorobenzene 98% 5 ML 190元
  • Alfa Aesar:1-氯-4-氟苯,98% 1-Chloro-4-fluorobenzene, 98%(352-33-0)
  • 图谱信息:1-氯-4-氟苯(352-33-0)红外图谱(IR1) 1-氯-4-氟苯(352-33-0)核磁图( 13 CNMR) 1-氯-4-氟苯(352-33-0)质谱(MS) 1-氯-4-氟苯(352-33-0)Raman光谱 1-氯-4-氟苯(352-33-0)核磁图( 1 HNMR)
  • 用途一:用作医药、农药、液晶材料中间体
  • MOL 文件:352-33-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C6 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CH - C
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C13 to C37+

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