Dioxabenzofos 蔬果磷

CAS 3811-49-2 MFCD00210363

化学结构图

3811-49-2
SMILES: COP1(=S)OCc2ccccc2O1

化学属性

Mol. FormulaC8H9O3PS
Mol. Weight216.20
Density1.37
Melting Point55-56°C

别名和识别编码

Chemical NameDioxabenzofos 10 µg/mL in Cyclohexane
Synonym 2-Methoxy-4H-1,2,3-benzodioxaphosphorine-2-sulfide 2-Methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfid 2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulfide 2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulphide 2-methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfide 2-甲氧基4[H]-1,3,2-苯并二氧杂磷-2-硫化物,环-O,O-(亚甲基-邻亚苯基)-O-甲基硫代磷酸酯,水杨硫磷 4H-1,3,2-benzodioxaphosphorin, 2-methoxy-, 2-sulfide o-methyl cyclic o,o-(methylene-o-phenylene)phosphorothioate Dioxabenzofos Fenphosphorin K-9 Phosphorothioic acid, cyclic O,O-(methylene-o-phenylene) O-methyl ester Salithion Salithion-sumitomo benzyl alcohol, o-hydroxy-, cyclic o,o-ester with o-methylphosphorothioate dioxabenzofos dioxabenzophos phosphorothioic acid, o
CAS Number3811-49-2
Chemical Name Translation蔬果磷
Wiswesser Line NotationT66 BOPO EHJ CS CO1
Beilstein Registry Number1875270
PubChem Substance ID19657
InChIInChI=1S/C8H9O3PS/c1-9-12(13)10-6-7-4-2-3-5-8(7)11-12/h2-5H,6H2,1H3
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; carbocycle; aromatic; alicycle; large ring; fused rings; 6ring; 10ring; 1fragment

产品应用

  • 蔬果磷是一种广谱高效低残留有机磷杀虫剂，主要用于防治作物地下害早，特别对棉花后期棉铃虫、柑桔介壳虫及蔬菜的多类害虫药效显著。

相关文献及参考

  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSDF4375000 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 88 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 29,243,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C268,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,308,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 110 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - structural change in nerve or sheath
   Behavioral - ataxia
REFERENCE :
   BOCKAF Bochu Kagaku.  Scientific Pest Control.  (Kyoto, Japan)  V.1-42,
   1937-77.  Discontinued.  Volume(issue)/page/year: 40,49,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent -

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,185,1983

Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H370 Causes damage to organs 导致器官损伤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P352
  • P307+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 在水中的溶解度为58mg/L（30℃），能与丙酮、苯、乙醇和乙醚混溶，在弱酸或碱性介质中稳定。

系列性分类

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