1-Trimethylsilyl-1-Hexyne 1-三甲基硅基-1-己炔

CAS 3844-94-8 MFCD00075407

化学结构图

3844-94-8
SMILES: CCCCC#C[Si](C)(C)C

化学属性

Mol. FormulaC9H18Si
Mol. Weight154.32
Refractive indexn20/D 1.431(lit.)
Boiling Point65 °C at 35 mmHg
Density0.764 g/mL at 25 °C(lit.)
Flash Point50 ºC

别名和识别编码

Chemical Name1-Trimethylsilyl-1-Hexyne
CAS Number3844-94-8
PubChem Substance ID586959
Beilstein Registry Number1421652
MDL NumberMFCD00075407
Synonym 1-Hexyn-1-yltrimethylsilane {LY} 1-Hexyn-1-yltrimethylsilane {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Hexyn-1
Chemical Name Translation1-三甲基硅基-1-己炔
LabNetwork Molecule IDLN00197994
InChIInChI=1S/C9H18Si/c1-5-6-7-8-9-10(2,3)4/h5-7H2,1-4H3
Canonical SMILESCCCCC#C[Si](C)(C)C
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分类

  • {SA} Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
  • Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
  • {SNA} Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks

产品应用

  • 1-己炔衍生物; SnCl4 和 ZnCl2 催化的和缩醛的偶联反应；和烯丙基试剂反应生成cyclopentanoids。

相关文献及参考

  • Beilstein: 4,IV,3940

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1993 UN 1993 3/PG 3
Packing GroupIII
Hazard Class3.2
Storage condition

其他信息

  • TSCA:No
  • 用途一:1-己炔衍生物; SnCl4 和 ZnCl2 催化的和缩醛的偶联反应；和烯丙基试剂反应生成cyclopentanoids。
  • MOL 文件:3844-94-8.mol
  • Sigma Aldrich:3844-94-8(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  5. Internal - Alkynes

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