2,4-Dibromothiazole 2,4-二溴噻唑

CAS 4175-77-3 MFCD01318994

化学结构图

4175-77-3
SMILES: Brc1csc(Br)n1

化学属性

Mol. FormulaC3HBr2NS
Mol. Weight242.92
Melting Point80-84°C
Density1.422
TSCANo
Boiling Point242.8°C at 760 mmHg

别名和识别编码

Chemical Name2,4-Dibromothiazole
CAS Number4175-77-3
Alfabeta NameDIBROMOTHIAZOLE 24-,
MDL NumberMFCD01318994
Synonym 2,4-Dibromothiazole {LY} 2,4-Dibromothiazole {} {LY} 2,4-Dibromothiazole {} {} {LY} 2,4-Dibromothiazole {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {}
EC Number250-023-7
Beilstein Registry Number2384789
PubChem Substance ID2763297
Reaxys-RN507628
Chemical Name Translation2,4-二溴噻唑
LabNetwork Molecule IDLN00116357
InChIInChI=1S/C3HBr2NS/c4-2-1-7-3(5)6-2/h1H
Canonical SMILESBrC1=NC(Br)=CS1
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分类

  • Sulfur & Selenium Compounds
  • Heterocycles
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • {SNA} Building Blocks, C3 to C7, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiazoles
  • Aromatics

产品应用

  • 2,4-Dibromothiazole is an intermediate used in the preparation of various 2,4-disubstituted thiazole derivatives with biologically active properties such as survival motor neuron (SMN) protein modula

相关文献及参考

  • Xiao, J. et al.: J. Med. Chem., 54, 6215 (2011); Dash, J. et al.: Tetrahed. Lett., 52, 2246 (2011);

安全信息

Warnings IRRITANT, KEEP COLD
Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn Xn,Xi
Storage condition -20°C {LY} -20°C Keep Cold {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 下游产品:
  • Sigma Aldrich:4175-77-3(sigmaaldrich)
  • Acros Organics:2,4-Dibromothiazole, 97+%(4175-77-3)
  • MOL 文件:4175-77-3.mol
  • 2,4-二溴噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 5G 2160元 2011/04/16 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 25G 7320元 2011/04/16 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 1G 709元
  • 2,4-二溴噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 5G 2050元 2014/06/02 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 25G 6930元 2014/06/02 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 1G 671元
  • 检测方法:HPLC
  • 用途一:用作有机合成中间体
  • Hazard Note:Harmful
  • 上游原料:氧溴化磷 --> 石脑油,原油
  • TCI Shanghai:2,4-二溴噻唑 2,4-Dibromothiazole,>;98.0%(GC)(4175-77-3)

系列性分类


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