2-(Hydroxymethyl)-4,5,6,7-Tetrahydro-1H-Isoindole-1,3(2H)-Dione N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺
CAS 4887-42-7 MFCD00051728
化学结构图
SMILES: O=C1C2=C(CCCC2)C(=O)N1CO
化学属性
| Mol. Formula | C9H11NO3 |
|---|---|
| Mol. Weight | 181.19 |
| Melting Point | 81-85 °C |
| TSCA | No |
| Appearance | 本品为无色结晶或稍具绿黄色结晶，m.p.80～82℃，相对密度 1.4600，微溶于水，易溶于苯、氯仿、二氯乙烷、乙醇、甲苯等有机溶剂，难溶于石油醚。 |
| Boiling Point | 314.29 °C at 760 mmHg |
别名和识别编码
| Chemical Name | 2-(Hydroxymethyl)-4,5,6,7-Tetrahydro-1H-Isoindole-1,3(2H)-Dione |
|---|---|
| MDL Number | MFCD00051728 |
| EC Number | 225-500-8 |
| CAS Number | 4887-42-7 |
| Beilstein Registry Number | 1531064 |
| PubChem Substance ID | 78597 |
| Synonym | 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxymethyl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)- |
| Chemical Name Translation | N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺 |
| InChIKey | QQHOVRKETYPQHY-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00241521 |
| InChI | InChI=1S/C9H11NO3/c11-5-10-8(12)6-3-1-2-4-7(6)9(10)13/h11H,1-5H2 |
| Canonical SMILES | O=C(N1CO)C2=C(CCCC2)C1=O |
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信息真实价格透明
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分类
- {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Cyclic Imides, Organic Building Blocks
- {Chemicalbook} 农药中间体: 杀虫剂中间体: 拟除虫菊酯类杀虫剂
安全信息
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S22 Do not breathe dust 不要吸入粉尘；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MSDS 信息:3,4,5,6-Tetrahydro-N-(hydroxymethyl)phthalimide(4887-42-7).msds
- 用途一:N-羟甲基-3，4，5，6-四氢邻苯二甲酰亚胺(简称胺醇)是卫生用杀虫剂胺菊酯的重要中间体。
- 上游原料:甲醛 --> Α-球蛋白 --> 1,3-丁二烯 --> 红霉素月桂酸酯 --> 精胺 --> 四氢苯酐 --> 四氢化邻苯二甲酸酐 --> 3,4,5,6-四氢苯酐 --> 3,4,5,6-四氢邻苯二甲酰亚胺
- 方法一:胺醇是由丁二烯与顺丁二烯酸酐通过Diels-Aldor反应先制得1，2，3，6-四氢邻苯二甲酸酐(简称四氢苯酐或△ 4 )，然后由△ 4 经异构化制得3，4，5，6-四氢邻苯二甲酸酐(简称△ 1 )，最后由△ 1 通过氨化、羟甲基化而制得。 在反应器中加入3，4，5，6-四氢邻苯二甲酰亚胺、37％甲醛溶液、稀氢氧化钠溶液，以二氯乙烷为溶剂，搅拌加热回流，冷却分层进行后处理，减压蒸馏得黏稠状的粗胺醇，用甲苯重结晶，可得到纯度为97％的精胺醇。
- Sigma Aldrich:4887-42-7(sigmaaldrich)
- N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 343870250 N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺 N-Hydroxymethyl-3,4,5,6-tetrahydrophthalimide 98% 25 GR 1803元 2010/06/21 343870050 N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺 N-Hydroxymethyl-3,4,5,6-tetrahydrophthalimide 98% 5 GR 699元
- Alfa Aesar:N-Hydroxymethyl-3,4,5,6-tetrahydrophthalimide, 98%(4887-42-7)
- MOL 文件:4887-42-7.mol
- Acros Organics:N-羟甲基-四羟基邻苯二胺 N-Hydroxymethyl-3,4,5,6-tetrahydrophthalimide, 98%(4887-42-7)
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