Bis(Perfluorophenyl)(Phenyl)Phosphine 双(五氟苯基)苯膦

CAS 5074-71-5 MFCD00000291

化学结构图

5074-71-5
SMILES: Fc1c(F)c(F)c(P(c2ccccc2)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

化学属性

Mol. FormulaC18H5F10P
Mol. Weight442.20
Melting Point58.0 to 62.0 deg-C
Flash Point>110°(230°F)
TSCANo
Boiling Point105°/0.3mm
Appearance white pwdr.
Stabilityair sensitive

别名和识别编码

Chemical NameBis(Perfluorophenyl)(Phenyl)Phosphine
Synonym Decafluorotriphenylphosphine {LY} Decafluorotriphenylphosphine {} {LY} Decafluorotriphenylphosphine {} {} {LY} Decafluorotriphenylphosphine {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {
CAS Number5074-71-5
PubChem Substance ID253662383
EC Number225-780-1
Beilstein Registry Number6253897
MDL NumberMFCD00000291
Chemical Name Translation双(五氟苯基)苯膦
Reaxys-RN949443
InChIKeyOYNXPGGNQMSMTR-UHFFFAOYSA-N
LabNetwork Molecule IDLN01740871
Canonical SMILESFC1=C(C(P(C2=CC=CC=C2)C3=C(C(F)=C(C(F)=C3F)F)F)=C(C(F)=C1F)F)F
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分类

  • {SNA} Additional Standards, Analytical Standards, MS Markers, MS Standards, Organic Pollutant Standards, Perfluoro Compounds, Physical Properties Standards, Single Compounds, Spectroscopy, 分析/色谱
  • {SNA} Analytical Standards, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy, 分析/色谱
  • {SNA} Analytical Standards,
  • {SA} Analytical Standards, Analytical/Chromatography, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy
  • 600 Series Wastewater Methods, 8000 Series Solidwaste Methods,

相关文献及参考

  • FT-IR 1 (2), 543:C / FT-IR 2 (2), 3317:D / FT-NMR 1 (2), 1657:B / IR-Spectra (3), 1182:H / NMR-Reference 2 (2), 879:A / RegBook 1 (2), 2265:F / Structure Index 1 , 354:B:8

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi,Xn,T,F Xi
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
UN Number UN 1593 6.1/PG 3

其他信息

  • Alfa Aesar:双(五氟苯基)苯膦,97% Bis(pentafluorophenyl)phenylphosphine, 97%(5074-71-5)
  • Sigma Aldrich:5074-71-5(sigmaaldrich)
  • Acros Organics:十氟三苯基磷 Bis(pentafluorophenyl)phenylphosphine, tech., 90%(5074-71-5)
  • 十氟三苯基磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 313171000 十氟三苯基磷 Bis(pentafluorophenyl)phenylphosphine 90%, tech. 100 MG 549元 2010/05/25 A11014 双(五氟苯基)苯膦,97% Bis(pentafluorophenyl)phenylphosphine, 97% 250mg 692元 2010/05/25 A11014 双(五氟苯基)苯膦,97% Bis(pentafluorophenyl)phenylphosphine, 97% 1g 2212元
  • Hazard Note:Irritant
  • MOL 文件:5074-71-5.mol

系列性分类


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