1-(2-Chlorophenyl)-2-Thiourea 邻氯苯基硫脲

CAS 5344-82-1 MFCD00004934

化学结构图

5344-82-1
SMILES: NC(=S)Nc1ccccc1Cl

化学属性

Mol. FormulaC7H7ClN2S
Mol. Weight186.66
Melting Point144-149 °C
TSCAYes
Appearance 本品为白色或淡黄色固体，m.p.143～146℃，易溶于乙醇，易溶于水。
Boiling Point250 °C at 760 mmHg

别名和识别编码

Chemical Name1-(2-Chlorophenyl)-2-Thiourea
Synonym 1-(2-Chlorophenyl)-2-thiourea {LY} 1-(2-Chlorophenyl)-2-thiourea {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(2-Chlorophenyl)-2-thiourea {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00004934
CAS Number5344-82-1
EC Number226-291-6
Beilstein Registry Number776946
Chemical Name Translation邻氯苯基硫脲
Wiswesser Line NotationSUYZMR BG
LabNetwork Molecule IDLN00111028
PubChem Substance ID737139
InChIInChI=1S/C7H7ClN2S/c8-5-3-1-2-4-6(5)10-7(9)11/h1-4H,(H3,9,10,11)
Canonical SMILESClC1=CC=CC=C1NC(N)=S
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {Chemicalbook} 农药中间体: 除草剂中间体: 其他类除草剂

相关文献及参考

  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSYS7100000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Packing GroupI
UN Number
Risk Statements
GHS Symbol
WGK Germany3
Precautionary statements
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H300 Fatal if swallowed 吞食致命
Signal word
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes T+
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 90,260,1947

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 方法一:其制备方法是在反应锅中加入邻氯苯胺和水，再滴加硫酸，温度控制在不高于50℃，反应约0.5h，再搅拌0.5h，然后加入硫氰化铵，搅拌升温回流20h，反应结束，过滤、干燥得产品。
  • Alfa Aesar:2-氯苯基硫脲,98% N-(2-Chlorophenyl)thiourea, 98%(5344-82-1)
  • 用途一:邻氯苯基硫脲是除草剂草除灵的中间体。
  • 邻氯苯基硫脲价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 185270050 邻氯苯基硫脲 1-(2-Chlorophenyl)-2-thiourea 98% 5 GR 636元 2010/05/25 L05711 2-氯苯基硫脲, 98% N-(2-Chlorophenyl)thiourea, 98% 5g 154元 2010/05/25 L05711 2-氯苯基硫脲, 98% N-(2-Chlorophenyl)thiourea, 98% 25g 385元
  • 下游产品:草除灵 --> 2-氨基-4-氯苯并噻唑
  • 上游原料:硫氰酸铵 --> 2-氯苯胺
  • Sigma Aldrich:5344-82-1(sigmaaldrich)
  • MOL 文件:5344-82-1.mol
  • MSDS 信息:1-(2-Chlorophenyl)-2-thiourea(5344-82-1).msds
  • Acros Organics:1-(2-氯苯基)-2-硫脲 1-(2-Chlorophenyl)-2-thiourea, 98%(5344-82-1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thioureas - Sulfur Compounds