2-Hydroxy-9H-fluoren-9-one 2-羟基-9H-芴-9-酮
CAS 6949-73-1 MFCD00001155
化学结构图
SMILES: O=C1c2ccccc2-c2ccc(O)cc21
化学属性
| Mol. Formula | C13H8O2 |
|---|---|
| Mol. Weight | 196 |
| Melting Point | 204-206 |
别名和识别编码
| Chemical Name | 2-Hydroxy-9H-fluoren-9-one |
|---|---|
| Synonym | 2-Hydroxy-9H-fluoren-9-one 2-羟基-9-芴 2-羟基-9-芴酮 NSC 22835 |
| MDL Number | MFCD00001155 |
| PubChem Substance ID | 81386 |
| CAS Number | 6949-73-1 |
| EC Number | 230-119-5 |
| Reaxys-RN | 1871045 |
| Beilstein Registry Number | 1871045 |
| Chemical Name Translation | 2-羟基-9H-芴-9-酮 |
| InChIKey | GXUBPHMYNSICJC-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00193240 |
| InChI | InChI=1S/C13H8O2/c14-8-5-6-10-9-3-1-2-4-11(9)13(15)12(10)7-8/h1-7,14H |
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分类
- Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
- {SA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
产品应用
- Reactant involved in:
- 1.One-pot synthesis of aryl substituted aurones.
- 2.Studies to tune HOMO-LUMO levels of 9-fluorenone scaffolds.
- 3.O-methylation for synthesis of second-generation light driven rotary molecular motors.
- 4.Reactions with aluminum, gallium compounds, and methylquinolines.
- 5. Synthesis of acridinyl- and fluorenylidenehydrazido calixarenes.
- 6.Acetylation for synthesis of acetates.
相关文献及参考
- 1. C. M. Sousa, et al., One pot synthesis of aryl substituted aurones Dyes and Pigments 92 , 537-541, (2012)
- 2. G. L. Eakins, et al., Tuning HOMO-LUMO levels: trends leading to the design of 9-fluorenone scaffolds with predictable electronic and optoelectronic properties J. Phys. Org. Chem. 24 , 1119-1128, (2011)
- 3. T. C. Pijper, et al., An enantioselective synthetic route toward second-generation light-driven rotary molecular motors J. Org. Chem. 75 , 825-838, (2010)
- 4. J. C. Deaton, et al., , The blue aluminum and gallium chelates for OLEDs Inorg. Chim. Acta 361 , 1020-1035, (2008)
- 5. E. A. Alekseeva, et al., Synthesis of acridinyl- and fluorenylidenehydrazido derivatives of p -tert-butylcalix[4]arene Russ. J. Gen. Chem. 77 , 1062-1065, (2007)
- 6. A. Kamal, et al., Al(OTf)3 as a highly efficient catalyst for the rapid acetylation of alcohols, phenols, and thiophenols under solvent-free conditions Tetrahedron Lett. 48 , 3813-3818, (2007)
- Beil. 8 ,188
- FT-IR 2 (2), 2477:B / FT-IR 1 (2), 76:A / FT-NMR 1 (2), 905:B / IR-Spectra (2), 782:D / IR-Spectra (3), 894:F / NMR-Reference 2 (2), 82:D / RegBook 1 (2), 1679:H / Structure Index 1 , 266:B:4
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:6949-73-1.mol
- 图谱信息:2-羟基-9-芴(6949-73-1)质谱(MS) 2-羟基-9-芴(6949-73-1)红外图谱(IR1) 2-羟基-9-芴(6949-73-1)红外图谱(IR2)
- Acros Organics:2-羟基-9-芴 2-Hydroxy-9-fluorenone, 97%(6949-73-1)
- 2-羟基-9-芴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0329 2-羟基-9-芴酮 2-Hydroxy-9-fluorenone 1G 1180元 2010/06/21 121250050 2-羟基-9-芴 2-Hydroxy-9-fluorenone 97% 5 GR 3817元 2010/06/21 121250010 2-羟基-9-芴 2-Hydroxy-9-fluorenone 97% 1 GR 1087元
- Sigma Aldrich:6949-73-1(sigmaaldrich)
- TCI Shanghai:2-羟基-9-芴酮 2-Hydroxy-9-fluorenone,>;90.0%(LC)(T)(6949-73-1)
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