2,4,6-Tri-tert-butylphenol 2,4,6-三叔丁基苯酚

CAS 732-26-3 MFCD00008821

化学结构图

732-26-3
SMILES: CC(C)(C)c1cc(C(C)(C)C)c(O)c(C(C)(C)C)c1

化学属性

Mol. FormulaC18H30O
Mol. Weight262.44
Boiling Point278 °C at 760 mmHg
Melting Point125-130°C
Density0.911
Solubility不溶
Stability对湿度敏感
Flash Point130 °C
pH:A

别名和识别编码

Chemical Name2,4,6-Tri-tert-butylphenol
CAS Number732-26-3
PubChem Substance ID12902
EC Number211-989-5
Beilstein Registry Number1913256
MDL NumberMFCD00008821
Reaxys-RN1913256
Synonym 2,4,6-Tri-tert-butylphenol {LY} 2,4,6-Tri-tert-butylphenol 2,4,6-tri-tert-butylphenol {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tri-tert-butylphenol
Chemical Name Translation2,4,6-三叔丁基苯酚
LabNetwork Molecule IDLN00202597
InChIInChI=1S/C18H30O/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11,19H,1-9H3
Canonical SMILESOC1=C(C(C)(C)C)C=C(C(C)(C)C)C=C1C(C)(C)C
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分类

  • {SA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

产品应用

  • 有机合成。航空气油抗氧剂。天然胶和合成胶的防老剂。合成胶低效稳定剂。聚烯和高冲击聚苯乙烯的热稳定剂。

相关文献及参考

  • Beilstein: 6,IV,3539
  • Short: IV/8A
  • Short: IV/8I
  • Short: IV/20B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes F,C,N,Xi,Xn Xn,N Xi
RTECSSN3570000
Precautionary statements
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P350
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number UN 2430 8/PG 3 3077 2430
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R11 Highly flammable 非常易燃
  • R51/53
  • R34 Causes burns 会导致灼伤
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Packing GroupIII
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class9
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1670 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
   Liver - other changes
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tuberculosis and
   Cancer, 4-1 Seiryo-machi, Sendai, Japan)  V.1-   1949-
   Volume(issue)/page/year: 36(1-4),10,1989

其他信息

  • Acros Organics:2,4,6-三叔丁基苯酚 2,4,6-Tri-tert-butylphenol, 97%(732-26-3)
  • F:8-23
  • MOL 文件:732-26-3.mol
  • Sigma Aldrich:732-26-3(sigmaaldrich)
  • 上游原料:三氯化铝 --> 苯酚 --> 氯代叔丁烷
  • 用途二:用于塑料和橡胶的防老剂
  • MSDS 信息:2,4,6-Tri-tert-butylphenol(732-26-3).msds
  • 白色或略带浅黄色结晶性粉末。无气味。易溶于乙醇、乙醚和丙酮等大多数有机溶剂,不溶于水。有毒。有刺激性。
  • 外观性质:白色或略带浅黄色结晶性粉末。无气味。易溶于乙醇、乙醚和丙酮等大多数有机溶剂,不溶于水。有毒。有刺激性。密度:0.864熔点:131℃沸点:278℃
  • 用途三:有机合成。航空气油抗氧剂。天然胶和合成胶的防老剂。合成胶低效稳定剂。聚烯和高冲击聚苯乙烯的热稳定剂。
  • 2,4,6-三叔丁基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 139330050 2,4,6-三叔丁基苯酚 2,4,6-Tri-tert-butylphenol 97% 5 GR 255元 2010/06/21 139330500 2,4,6-三叔丁基苯酚 2,4,6-Tri-tert-butylphenol 97% 50 GR 470元 2010/06/21 139335000 2,4,6-三叔丁基苯酚 2,4,6-Tri-tert-butylphenol 97% 500 GR 3991元
  • 用途一:用作天然橡胶防老剂和合成橡胶低效稳定剂

系列性分类


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