2-Iodopropane 2-碘丙烷

CAS 75-30-9 MFCD00001071

化学结构图

75-30-9
SMILES: CC(C)I

化学属性

Mol. FormulaC3H7I
Mol. Weight170
Density1.7
Refractive index1.4950 to 1.5010
Boiling Point
Melting PointN/A
Flash Point42°C(lit.)
TSCAYes
Stability对光和空气敏感
Solubility微溶于水，可混溶于醇、苯、氯仿、醚。

别名和识别编码

Chemical Name2-Iodopropane
Synonym 1-methylethyl iodide 2-IODOPROPANE, STAB. WITH SILVER WOOL 2-Iodopropane 2-Iodopropane (Stabilized with Copper) {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number75-30-9
EC Number200-859-3
Beilstein Registry Number1098244
MDL NumberMFCD00001071
PubChem Substance ID6362
Merck Number5214
Reaxys-RN1098244
Chemical Name Translation2-碘丙烷
Wiswesser Line NotationIY1&1
LabNetwork Molecule IDLN00194376
InChIInChI=1S/C3H7I/c1-3(2)4/h3H,1-2H3
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • Usually used to prepare butyric and isobutyric acid.

相关文献及参考

  • Merck: 14,5214
  • Short: II/19b
  • Short: II/19c
  • Merck: 14,5214 Beilstein:1,114
  • Short: II/14a
  • The ring-opening of cyclic thionocarbonates followed by reductive elimination with zinc to give alkenes provides an alternative to the Corey-Winter desulfurization method (see Triethyl­ phosphite, L00339): Tetrahedron Lett., 3793 (1973).

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTZ4200000
Packing GroupIII
UN Number 2392 UN 2392 3/PG 3
Storage condition +4°C 4 4℃ Light Sensitive Store at RT. 充氩保存 避光保存
Hazard Codes 3
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1190 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   35,1411,1975

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 320 gm/m3/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAVUAI Fiziologicheski Aktivnye Veshchestva.  Physiologically Active
   Substances.  (Izdatel'stvo Naukova Dumka, Kiev, USSR)  No.1-    1966-
   Volume(issue)/page/year: 7,35,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,756,1969

Restrict 危险品

其他信息

  • 灭火剂:泡沫、雾状水、干粉、砂土
  • 用途二:用作溶剂，并用于有机合成。
  • Sigma Aldrich:75-30-9(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 毒性分级:中毒
  • 微溶于水，可混溶于醇、苯、氯仿、醚。
  • F:8
  • 外观性质:无色液体,在空气中和光照下易变色。
  • Acros Organics:2-碘代丙烷 2-Iodopropane, stabilized, 98+%(75-30-9)
  • Alfa Aesar:2-碘丙烷,98%,stab.withcopper 2-Iodopropane, 98+%, stab. with copper(75-30-9)
  • MSDS 信息:异丙基碘(75-30-9).msds
  • 用途一:用作溶剂，也用于医药及有机合成
  • 2-碘代丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80111480 碘代异丙烷 100ml 375元 2011/08/23 80111426 碘代异丙烷 100ml 158元 2011/04/16 I0069 2-碘丙烷(含稳定剂铜屑) 2-Iodopropane (stabilized with Copper chip) 500G 1830元
  • TCI Shanghai:2-碘丙烷(含稳定剂铜屑) 2-Iodopropane (stabilized with Copper chip),>;98.0%(GC)(75-30-9)
  • MOL 文件:75-30-9.mol
  • 可燃性危险特性:明火可燃; 高热放出有毒碘化物气体
  • 敏感性:Light Sensitive
  • 图谱信息:2-碘代丙烷(75-30-9)核磁图( 13 CNMR) 2-碘代丙烷(75-30-9)核磁图( 1 HNMR) 2-碘代丙烷(75-30-9)质谱(MS) 2-碘代丙烷(75-30-9)红外图谱(IR1)
  • 急性毒性:腹腔- 小鼠 LD50: 1300 毫克/ 公斤
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl