Tribromoacetic Acid 三溴乙酸

CAS 75-96-7 MFCD00004167

化学结构图

75-96-7
SMILES: O=C(O)C(Br)(Br)Br

化学属性

Mol. FormulaC2HBr3O2
Mol. Weight297
Melting Point130.0 to 134.0 deg-C
TSCAYes
Boiling Point245 °C(lit.)
Flash Point244-246°C
Solubility溶于水、乙醇、乙醚，不溶于石油醚。

别名和识别编码

Chemical NameTribromoacetic Acid
CAS Number75-96-7
EC Number200-919-9
Synonym 2,2,2-Tribromoacetic acid Acetic acid, tribromo- RARECHEM AL BE 0117 TRIBROMOACETATE TRIBROMOACETIC ACID TRIBROMOACETIC ACID, 100MG, NEAT Tribromacetic Tribromacetic acid Tribromessigsäure Tribromoacetic acid solution Tribromoacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00004167
Reaxys-RN1755150
Beilstein Registry Number2,220
PubChem Substance ID87576321
Merck Number9609
Chemical Name Translation三溴乙酸
LabNetwork Molecule IDLN00193349
InChIInChI=1S/C2HBr3O2/c3-2(4,5)1(6)7/h(H,6,7)
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分类

  • {SNA} Chemical Synthesis, Organic Acids, Synthetic Reagents
  • {SNA} Acids, Acids & Bases, Chemical Synthesis, Organic Acids, Synthetic Reagents
  • {uni_hamburg} no charge; carboxylic acid; 1fragment
  • 500 Series Drinking Water Methods, Analytical Standards, Analytical/Chromatography, Bromo, Chemical Class, Chromatography, EPA, Food & Beverage Standards, Halogenated, Method 552, Method Specific, Organic Acids

相关文献及参考

  • Merck 14 ,9609
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zn ... Bi. Diagrams, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31b Year: 1993 Keyword: NQR ISBN: 3-540-55147-6 ISBN: 978-3-540-55147-8 Internet Resource: DOI:10.1007/b46097 RefComment: 147 figs., VIII, 347 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31,

安全信息

Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
Hazard Codes C C,Xi,F F,Xi
GHS Symbol
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger Warning {} {} {} {} {} {} {} {} {} {} {TCI}
UN Number 3261 UN 3261 8/PG 2 UN3261
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Packing GroupII
Hazard Class8
Storage condition 2-8°C
Warnings 危化品目录(2015) 危险化学品

其他信息

  • Sigma Aldrich:75-96-7(sigmaaldrich)
  • MSDS 信息:三溴乙酸(75-96-7).msds
  • Acros Organics:Tribromoacetic acid, 99%(75-96-7)
  • F:8
  • TCI Shanghai:三溴乙酸 Tribromoacetic Acid,>;98.0%(T)(75-96-7)
  • 图谱信息:三溴乙酸(75-96-7)红外图谱(IR3) 三溴乙酸(75-96-7)红外图谱(IR1) 三溴乙酸(75-96-7)红外图谱(IR2) 三溴乙酸(75-96-7)Raman光谱 三溴乙酸(75-96-7)核磁图( 13 CNMR) 三溴乙酸(75-96-7)质谱(MS)
  • Alfa Aesar:三溴乙酸,97% Tribromoacetic acid, 97%(75-96-7)
  • 用途一:主要用于有机合成和精细化工
  • 三溴乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0351 三溴乙酸 Tribromoacetic Acid 500G 3680元 2014/06/02 T0351 三溴乙酸 Tribromoacetic Acid 25G 423元 2010/06/21 139300250 三溴乙酸 Tribromoacetic acid 99% 25 GR 572元
  • MOL 文件:75-96-7.mol
  • 外观性质:无色有光泽的片状结晶。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Food & Beverage Standards - Chromatography
  5. Organic Acids - Food & Beverage Standards
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Bromo 溴化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. EPA - Method Specific
  5. 500 Series Drinking Water Methods - EPA
  6. Method 552 - 500 Series Drinking Water Methods
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TP - TZ - T

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