Phosphorus pentafluoride 氟化磷(V)

CAS 7647-19-0 MFCD00040326

化学结构图

7647-19-0
SMILES: FP(F)(F)(F)F

化学属性

Mol. FormulaF5P
Mol. Weight125.97
Density5.805
Melting Point-93.8°
TSCAYes
Boiling Point-84.6°
Flash Point-84.6°C

别名和识别编码

Chemical NamePhosphorus(V) fluoride
Synonym phosphoric fluoride PHOSPHORUS (V) FLUORIDE Phosphorus(V)pentafluoride 氟化磷(V) PHOSPHORUS PENTAFLUORIDE pentafluoro-phosphoran Pentafluorophosphorane phosphorane,pentafluoro- pentafluorophosphorus PF5 phosphorusfluoride(pf5) phosphorane, pentafluoro- pentafluoro-Phosphorane Pentafluorophosphorus(V) Phosphorpentafluorid 氟化磷 AURORA KA-1084 fluoride,penta-phosphoru 五氟化磷 phosphorus fluoride POSPHORUS PENTAFLUORIDE Phosphorus fluoride (PF5) Phosphorus(V) fluoride phosphorus (V) fluoride phosphorus pentafluoride Phosphorous pentafluoride Phosphorane, pentafluoro- Phosphoruspentafluoride99%
MDL NumberMFCD00040326
CAS Number7647-19-0
EC Number231-602-3
Merck Number14,7352
Chemical Name Translation氟化磷(V)
LabNetwork Molecule IDLN02143597
PubChem Substance ID24295
InChIInChI=1S/F5P/c1-6(2,3,4)5
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分类

  • {Chemicalbook} 无机化工产品: 无机盐: Cm磷化合物及磷酸盐
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Ha

安全信息

RTECSTH4070000
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
UN Number UN2198 2198
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23 Toxic by inhalation 吸入有毒
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
Storage condition Moisture Sensitive
Hazard Class2.3
Hazard Codes C,T
Warnings 危化品目录(2015) 危险化学品
Hazard statements
  • H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P410+P403
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 毒性:在潮湿空气中产生有毒和腐蚀性的氟化氢烟雾。对皮肤、眼睛、黏膜呈剧烈刺激作用，吸入可引起呼吸道炎症，肺水肿。应使吸入气体的患者脱离污染区，安置休息并保暖，严重者须就医诊治。不慎溅人眼睛要用大量水冲洗15min，并就医诊治。皮肤如污染用大量水冲洗，如灼伤须就医诊治。
  • Hazard Note:Toxic/Corrosive
  • MOL 文件:7647-19-0.mol
  • 用途一:用作聚合反应催化剂。电子工业。
  • 灭火剂:水
  • MSDS 信息:五氟化磷(7647-19-0).msds
  • 储运特性:库房通风低温干燥; 与碱、含水物品分开存放
  • 可燃性危险特性:遇水分解有毒氟化氢气体
  • 外观性质:无色、有刺激性恶臭味的气体，在潮湿空气中剧烈发烟。
  • 类别:压缩气体和液化气体
  • Alfa Aesar:Phosphorus(V) fluoride(7647-19-0)
  • 职业标准:TLV-TWA 2.5 毫克(氟)/立方米; STEL 5 毫克(氟)/立方米
  • 参考质量标准:参考标准 指标名称 指标 五氟化磷(PF5)含量/% 99.0 比容/(m 3 /kg) 0.19
  • 方法一:将三氟化磷加入反应器中，再通入氟气进行反应，生成五氟化磷气体，经冷却捕集器，制得五氟化磷成品。其 PF3+F2→PF5
  • 敏感性:Moisture Sensitive
  • 上游原料:氟氯菊酯 --> 氟 --> 荧光增白剂PF

系列性分类

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