Molybdenum hexafluoride 氟化钼(VI)

CAS 7783-77-9 MFCD00014220

化学结构图

7783-77-9
SMILES: F[Mo](F)(F)(F)(F)F

化学属性

Mol. FormulaF6Mo
Mol. Weight209.95
Density2.3
Boiling Point37 °C at 760 mmHg
Melting Point17.5 °C
TSCAYes
Flash Point35°CC
Appearance 六氟化钼为白色立方结晶,极易吸潮,在潮湿空气中放出蓝白色烟雾,易挥发成气体。相对密度2.30,熔点17.5℃,沸点35℃,融熔热为4.33 kJ/tool,汽化热为27.7 kJ/mol。在水中能水解,能溶于无水氢氟酸中,溶解度为1.5 mol/1000 gHF。

别名和识别编码

Chemical NameMolybdenum hexafluoride
Synonym Molybdenum(VI) fluoride {LY} Molybdenum(VI) fluoride {} {LY} Molybdenum(VI) fluoride {} {} {LY} Molybdenum(VI) fluoride {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Molybdenum(VI) fluoride
MDL NumberMFCD00014220
CAS Number7783-77-9
PubChem Substance ID82219
EC Number232-026-5
Merck Number14,6237
Chemical Name Translation氟化钼(VI)
LabNetwork Molecule IDLN02144520
InChIInChI=1S/6FH.Mo/h6*1H;/q;;;;;;+6/p-6
Canonical SMILESF[Mo](F)(F)(F)(F)F
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分类

  • {SNA} Materials Science, Metal and Ceramic Science, Molybdenum Salts, Salts
  • {Chemicalbook} 无机化工产品: 无机盐: Cp钼、钛、钨、钒、锆化合物
  • {SA} Chemical Synthesis, Electronic Chemicals, Fluorides, Materials Science, Micro/NanoElectronics, Specialty Gases, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/31b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zn ... Bi. Diagrams, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31b Year: 1993 Keyword: NQR ISBN: 3-540-55147-6 ISBN: 978-3-540-55147-8 Internet Resource: DOI:10.1007/b46097 RefComment: 147 figs., VIII, 347 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included ar

安全信息

WGK Germany3
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312
  • P301+P330+P331
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
RTECSQA4681450
GHS Symbol
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
Packing GroupII
UN Number UN3289 UN 3264 8/PG 2
Risk Statements
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R34 Causes burns 会导致灼伤
  • R23 Toxic by inhalation 吸入有毒
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
Hazard Class6.1
Hazard Codes C

其他信息

  • MOL 文件:7783-77-9.mol
  • Acros Organics:六氟化钼 Molybdenum(VI) fluoride, 99.9+%(7783-77-9)
  • 上游原料:氟 --> 金属钼
  • Sigma Aldrich:7783-77-9(sigmaaldrich)
  • Alfa Aesar:氟化钼(VI) Molybdenum(VI) fluoride(7783-77-9)
  • 毒性:本品有毒,TLV值为5 mg/m 3 。
  • 六氟化钼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 22713 氟化钼(VI) Molybdenum(VI) fluoride 50g 10850元
  • Hazard Note:Corrosive
  • 敏感性:Hygroscopic
  • F:10-21
  • 参考质量标准:参考标准 指标名称 指标 六氟化钼(MoF6)/%≥ 99 氧(O2)/10 -6 < 200 氮(N2)/10 -6 < 300 氢(H2)/10 -6 < 30 活性氟(F)/10 -6 < 500
  • 用途一:用作强氟化剂、成膜材料及离子掺杂。
  • 方法一:合成法将冷的、干燥的氟气与金属钼于250~300℃直接进行氟化,其中MoF6粗品在-5~5℃回收,经真空蒸馏即可制得。

系列性分类


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