(+)-α-Pinene (+)-α-蒎烯
CAS 7785-70-8 MFCD00001346
化学结构图
SMILES: CC1=CC[C@@H]2C[C@H]1C2(C)C
化学属性
| Mol. Formula | C10H16 |
|---|---|
| Mol. Weight | 136.23 |
| Refractive index | 1.4650 to 1.4670 |
| Boiling Point | 155-156°C at 760 mmHg |
| Density | 0.858 |
| Melting Point | -62°C |
| Flash Point | 33°C |
| TSCA | Yes |
| Autoignition Point | 491 °F |
别名和识别编码
| Chemical Name | (+)-α-Pinene |
|---|---|
| Synonym | (1R)-α-Pinene {LY} (1R)-α-Pinene {} {LY} (1R)-α-Pinene {} {} {LY} (1R)-α-Pinene {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| Beilstein Registry Number | 2038653 |
| CAS Number | 7785-70-8 |
| PubChem Substance ID | 82227 |
| EC Number | 232-087-8 |
| MDL Number | MFCD00001346 |
| Reaxys-RN | 13246646 |
| Merck Number | 7445 |
| Chemical Name Translation | (+)-α-蒎烯 |
| LabNetwork Molecule ID | LN00195589 |
| InChI | InChI=1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9-/m1/s1 |
| Canonical SMILES | CC1(C)[C@]2([H])CC=C(C)[C@@]1([H])C2 |
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分类
- {SNA} Alphabetical Index of Analytical Standards, Chemical Class, All Alphabetically Sorted, Analytical Standards, Analytical/Chromatography, Chromatography, Flavors and Fragrances, Food & Beverage Standards, Food Products & Beverages, Herbs & Spices, Life Sciences Standards, M-R, Natural Compounds, Natural Terpene Standards, P, PER - POLA, Rosemary, Substance Classification, Terpene
- {SNA} A-D, Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O-P
- {SNA} Alphabetical Index of Analytical Sta
产品应用
- 用于制备手性硼氢化试剂。
相关文献及参考
- Forms a chiral adduct with diborane, useful for asymmetric hydroborations with high optical yields: J. Am. Chem. Soc., 99, 5514 (1977). Recrystallization of the borane adduct can be used to obtain a pure single diastereomer: J. Org. Chem., 49, 945 (1984). For reviews of the synthesis of pure enantiomers via chiral organoboranes, see: Acc. Chem. Res., 21, 287 (1988); and of asymmetric reduction with chiral organoboranes based on ɑ-pinene: Acc. Chem. Res., 25, 16 (1992).
- Short: III/38B
- Short: IV/16
- Short: I
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P302+P352
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P331 Do NOT induce vomiting.. 不要催吐。
- P332+P313
- P333+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
其他信息
- Sigma Aldrich:7785-70-8(sigmaaldrich)
- 蒎烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1099 (1R)-(+)-α-蒎烯 (1R)-(+)-alpha-Pinene 25ML 222元 2014/06/02 P1099 (1R)-(+)-α-蒎烯 (1R)-(+)-alpha-Pinene 500ML 1610元 2010/06/21 131261000 蒎烯 (1R)-(+)-alpha-Pinene 98%, 80% ee 100 GR 675元
- Acros Organics:(1R)-(+)-alpha-蒎烯 (1R)-(+)-alpha-Pinene, 80% ee, 98%(7785-70-8)
- Alfa Aesar:(+)-α-蒎烯,98% (+)-alpha-Pinene, 98%(7785-70-8)
- 图谱信息:蒎烯(7785-70-8)质谱(MS) 蒎烯(7785-70-8)核磁图( 1 HNMR) 蒎烯(7785-70-8)核磁图( 13 CNMR) 蒎烯(7785-70-8)红外图谱(IR1)
- TCI Shanghai:(1R)-(+)-α-蒎烯 (1R)-(+)-alpha-Pinene,>;95.0%(GC)(7785-70-8)
- 下游产品:(1S,2S,3R,5S)-(+)-2,3-蒎烷二醇
- 用途一:药品/化学原料药和中间体，如制备原料药孟鲁司特钠（顺尔宁）以及恩替卡韦的中间体 ；该产品是光学拆分剂，还可应用于其他领域。
- F:10
- 检测方法:GC,Rotation,Moisture
- MOL 文件:7785-70-8.mol
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