2-​Propenoic acid, 2-​hydroxyethyl ester 2-羟基乙基丙烯酸酯

CAS 818-61-1 MFCD00002865

化学结构图

818-61-1
SMILES: C=CC(=O)OCCO

化学属性

Mol. FormulaCH2=CHCOOCH2CH2OH
Mol. Weight116
Refractive index1.4470 to 1.4520
Boiling Point90-92
Density1.011
Flash Point104°C(lit.)
TSCAYes
Melting Point-60
Vapor Density>;1 (vs air)
Vapor Pressure<;0.1 mmHg ( 20 °C)
Solubility可溶
Stability对光敏感

别名和识别编码

Chemical Name2-​Propenoic acid, 2-​hydroxyethyl ester
Synonym 2-(Acryloyloxy)ethanol Acrylic acid, 2-hydroxyethyl ester acrylic acid 2-hydroxy-ethyl ester HEA 2-Hydroxy Ethyl Acrylate (HEA) hydroxyethylacrylate Glycolmonoacrylate {Ch (2-Hydroxyethyl)-acrylat 2-Propenoicacid,2-hydroxyethylester Ethylene glycol, acrylate Viscoat 220 bisomer2hea 2-Propenoic acid, 2-hydroxyethyl ester 2-Hyd ACRYLICACID,HYDROXYETHYLESTER Rocryl 420 丙烯酸羟乙酯 Acrylsäure-2-hydroxyethylester 乙二醇单丙烯酸酯 2-Hydroxyethylester kyseliny akrylove 丙烯酸-2-羟乙基酯 Light Ester HOA Bisomer 2HEA acrylic acid-(2-hydroxy-ethyl ester) Ethylene glycol monoacrylate
CAS Number818-61-1
PubChem Substance ID87562286
EC Number212-454-9
Beilstein Registry Number969853
MDL NumberMFCD00002865
Reaxys-RN969853
Chemical Name Translation2-羟基乙基丙烯酸酯
Wiswesser Line NotationQ2OV1U1
LabNetwork Molecule IDLN00224663
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品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SA} Acrylate, Acrylic Monomers, Building Blocks,

相关文献及参考

  • Short: EINECS
  • Beilstein: 2,IV,1469
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T,N
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P303+P361+P353
  • P304+P340+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P308+P313
  • P403+P233
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P301+P330+P331+P310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P304+P340
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P330+P331
  • P304+P340+P312
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
Signal word
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
RTECSAT1750000
UN Number 2922 UN2927 UN 2927 6.1/PG 2
Storage condition Light Sensitive 密封保存 密封保存,储存温度2-8°C
Packing GroupII
Hazard Class8/6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - ptosis
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - alteration in gastric secretion
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(4),56,1980

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher informa

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 650 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 3/23/1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1010 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 18 mg/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 4,381,1989

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 15 mg/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 4,381,1989

其他信息

  • 下游产品:卡波姆树脂 --> 可结合抗甲胎蛋白的胶乳微球 --> 聚氨酯丙烯酸酯光固化涂料(I) --> 聚氨酯-丙烯酸酯
  • 上游原料:曙光红(四溴荧光素) -->
  • 毒性分级:中毒
  • 与水混溶,溶于一般有机溶剂。
  • TCI Shanghai:丙烯酸-2-羟乙基酯(含稳定剂甲氧基氢醌) 2-Hydroxyethyl Acrylate (stabilized with MEHQ),>;96.0%(GC)(818-61-1)
  • 储运特性:库房通风低温干燥
  • MOL 文件:818-61-1.mol
  • 类别:有毒物品
  • MSDS 信息:丙烯酸-2-羟乙酯(818-61-1).msds
  • 可燃性危险特性:可燃; 加热分解释放刺激烟雾
  • 方法一:丙烯酸与环氧乙烷在催化剂及阻聚剂存在下进行加成反应,生成丙烯酸-2-羟基乙基酯粗成品,经脱气、蒸馏得成品原料消耗定额:丙烯酸710kg/t、环氧乙烷485kg
  • 丙烯酸羟乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0743 丙烯酸-2-羟乙基酯(含稳定剂MEHQ) 2-Hydroxyethyl Acrylate (stabilized with MEHQ) 25ML 229元 2014/06/02 A0743 丙烯酸-2-羟乙基酯(含稳定剂MEHQ) 2-Hydroxyethyl Acrylate (stabilized with MEHQ) 500ML 410元 2010/06/21 334080010 丙烯酸羟乙酯 2-Hydroxyethyl acrylate 97%, stabilized 1 LT 1229元
  • {Chemicalbo
  • 用途一:用于辐射固化体系中的活性稀释剂和交联剂,亦可作为树脂交联剂,塑料、橡胶改性剂
  • 用途二:该品可与丙烯酸及酯、丙烯醛、丙烯腈、丙烯酰胺、甲基丙烯腈、氯乙烯、苯乙烯等很多单体进行共聚,所得产品可用于处理纤维,提高纤维的耐水性、耐溶剂性、防皱性和防水性;还用于制造性能优良的热固性涂料、合成橡胶,用作润滑油添加剂等。在粘合剂方面,与乙烯基单体共聚,可改进其粘接强度。在纸加工方面,用于制涂层用丙烯酸乳液,可提高其耐水性和强度。
  • 急性毒性:口服-大鼠 LD50: 650 毫克/公斤
  • 蒸气密度:>;1 (vs air)
  • 方法一:丙烯酸与环氧乙烷在催化剂及阻聚剂存在下进行加成反应,生成丙烯酸-
  • 图谱信息:丙烯酸羟乙酯(818-61-1)红外图谱(IR2) 丙烯酸羟乙酯(818-61-1)红外图谱(IR1) 丙烯酸羟乙酯(818-61-1)Raman光谱 丙烯酸羟乙酯(818-61-1)核磁图( 13 CNMR) 丙烯酸羟乙酯(818-61-1)核磁图( 1 HNMR) 丙烯酸羟乙酯(818-61-1)质谱(MS)
  • 蒸气压:<;0.1 mm Hg ( 20 °C)
  • 常规方法:镀锌铁桶包装。贮存于阴凉通风处。库房应专用,不与其他物品混贮。注意防火。贮存及运输前应加阻聚剂。
  • Sigma Aldrich:818-61-1(sigmaaldrich)
  • Alfa Aesar:2-羟基乙基丙烯酸酯,97%,stab.with200-300ppm4-methoxyphenol 2-Hydroxyethyl acrylate, 97%, stab. with 200-300ppm 4-methoxyphenol(818-61-1)
  • 防护措施:有一定毒性。大鼠经口LD50为 1.0g/kg。吸入后有明显的刺激作用。皮肤刺激程度较轻,但对眼部伤害较严重。 操作人员应戴防护眼镜。
  • F:8
  • Acros Organics:丙烯酸-2-羟乙酯 2-Hydroxyethyl acrylate, stabilized, 97%(818-61-1)
  • 外观性质:无色透明液体。

系列性分类


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