N-Vinyl-2-Pyrrolidinone 1-乙烯基-2-吡咯烷酮

CAS 88-12-0 MFCD00003197

化学结构图

88-12-0
SMILES: C=CN1CCCC1=O

化学属性

Mol. FormulaC6H9NO
Mol. Weight111.14
Density1.04
Autoignition Point685 °F
Refractive index1.5120 to 1.5150
Vapor Density3.8 (vs air)
Boiling Point217.6°C at 760 mmHg
Vapor Pressure0.1 mmHg ( 24 °C)
Flash Point93.9°C
TSCAYes
Melting Point13-14°C
SolubilityMISCIBLE
Stability对光和热敏感
pH:A

别名和识别编码

Chemical NameN-Vinyl-2-Pyrrolidinone
MDL NumberMFCD00003197
CAS Number88-12-0
EC Number201-800-4
Beilstein Registry Number110513
Synonym 1-Vinylpyrrolidin-2-one {LY} 1-Vinylpyrrolidin-2-one {} {LY} 1-Vinylpyrrolidin-2-one {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrrolidin-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Vinylpyrr
PubChem Substance ID6917
Merck Number14,7697
Reaxys-RN110513
Chemical Name Translation1-乙烯基-2-吡咯烷酮
Wiswesser Line NotationT5NVTJ A1U1
LabNetwork Molecule IDLN00196358
InChIInChI=1S/C6H9NO/c1-2-7-5-3-4-6(7)8/h2H,1,3-5H2
Canonical SMILESO=C1N(C=C)CCC1
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分类

  • {SNA} Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Materials Science, Monomers, Polymer Science, Pyrrolidines, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • {SNA} Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Monomers, Polymer Science, Pyrrolidines, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学
  • {SA} Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Pyrrolidines
  • {uni_hamburg} no charge; nitrogen heterocycle; alicycle; 5ring; amide; lactame; 1fragment

相关文献及参考

  • Merck: 14,7697 Beilstein: 21,V,6,330
  • Short: III/35E
  • Short: IV/17
  • Merck: 14,7697

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R48/20
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P361+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302+H332
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H318 Causes serious eye damage 严重伤害眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H302+H312+H332
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUY6107000
Packing GroupIII
UN Number 2810 UN2810
Hazard Codes 6.1 Xn
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1 
TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
   Liver - tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,1041,1997

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3200 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BurLW# Personal Communication from L.W. Burnette, Material Safety Dept., GAF
   Corp., 1361 Alps Rd., Wayne, NJ 07470, Nov. 2, 1978 Volume(issue)/page/year:
   02NOV1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 560 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BurLW# Personal Communication from L.W. Burnette, Material Safety Dept., GAF
   Corp., 1361 Alps Rd., Wayne, NJ 07470, Nov. 2, 1978 Volume(issue)/page/year:
   02NOV1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1470 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BurLW# Personal Communication from L.W. Burnette, Material Safety Dept., GAF
   Corp., 1361 Alps Rd., Wayne, NJ 07470, Nov. 2, 1978 Volume(issue)/page/year:
   02NOV1978

其他信息

  • 用途一:在化妆品、洗涤品、医药、感光材料等诸领域有广泛的应用
  • 常温下是一种无色或淡黄色略有气味的透明液体，易溶于水和其它多种有机溶剂，化学性质活泼易水解和聚合。N-乙烯基吡咯烷酮也是一种性能极其优异的有机溶剂。 爆炸极限expl. lim. 10 %，对光敏感。
  • Sigma Aldrich:88-12-0(sigmaaldrich)
  • 外观性质:常温下是一种无色或淡黄色略有气味的透明液体，易溶于水和其它多种有机溶剂，化学性质活泼易水解和聚合。N-乙烯基吡咯烷酮也是一种性能极其优异的有机溶剂。 爆炸极限expl. lim. 10 %，对光敏感。沸点：92-95℃/11 mmHg闪点：95 °C密度：1.04 折光率n20/D：1.512
  • MOL 文件:88-12-0.mol
  • Alfa Aesar:1-乙烯基-2-吡咯烷酮,99%stab.with0.1%sodiumhydroxide 1-Vinyl-2-pyrrolidinone, 99% stab. with 0.1% sodium hydroxide(88-12-0)
  • 下游产品:5-甲基吲哚 --> 聚乙烯吡咯烷酮
  • 蒸气密度:3.8 (vs air)
  • 图谱信息:N-乙烯基吡咯烷酮(88-12-0)质谱(MS) N-乙烯基吡咯烷酮(88-12-0)核磁图( 1 HNMR) N-乙烯基吡咯烷酮(88-12-0)红外图谱(IR1) N-乙烯基吡咯烷酮(88-12-0)核磁图( 13 CNMR)
  • 蒸气压:0.1 mm Hg ( 24 °C)
  • 上游原料:氢氧化钾 --> 镍 --> 乙二醇 --> 环己烷 --> 丁二酰亚胺
  • N-乙烯基吡咯烷酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 AV340902 1-乙烯基-2-吡咯烷酮;乙烯基吡咯烷酮;N-乙烯基-2-吡咯烷酮 250g 534元 2011/08/23 K9506001 N-乙烯基吡咯烷酮 250ml 400元 2011/04/16 V0026 1-乙烯基-2-吡咯烷酮(含稳定剂N,N'-二仲丁基对苯二胺) 1-Vinyl-2-pyrrolidone (stabilized with N,N'-Di-sec-butyl-p-phenylenediamine) 25ML 180元
  • 海关编码:29337900
  • Acros Organics:N-乙烯基-2-吡咯烷酮 N-Vinyl-2-pyrrolidone, stabilized with Kerobit(88-12-0)
  • 检测方法:GC,NMR
  • TCI Shanghai:1-乙烯基-2-吡咯烷酮(含稳定剂N,N'-二仲丁基对苯二胺) 1-Vinyl-2-pyrrolidone (stabilized with N,N'-Di-sec-butyl-p-phenylenediamine),>;99.0%(GC)(88-12-0)
  • MSDS 信息:1-Vinyl-2-pyrrolidone(88-12-0).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrroles 吡咯
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrrolidines 吡咯烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrrolidines 吡咯烷
  5. C4 to C10 - Pyrrolidines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Vinyl Ethers

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