2-(Triphenylphosphoranylidene)succinic anhydride 3-(三苯基磷酰胺)二氢呋喃-2,5-二酮

CAS 906-65-0 MFCD00005529

化学结构图

906-65-0
SMILES: O=C1CC(=P(c2ccccc2)(c2ccccc2)c2ccccc2)C(=O)O1

化学属性

Mol. FormulaC22H17O3P
Mol. Weight360.34
Melting Point167 °C
Boiling Point516.1±33.0 °C at 760 mmHg

别名和识别编码

Chemical Name3-(Triphenylphosphoranylidene)Dihydrofuran-2,5-Dione
MDL NumberMFCD00005529
PubChem Substance ID70183
CAS Number906-65-0
EC Number212-998-7
Chemical Name Translation3-(三苯基磷酰胺)二氢呋喃-2,5-二酮
Synonym 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Triphenylphosphoranylidene)dihydrofuran-2,5-dione {} {} {} {} {} {} {} {} {} {} {}
InChIKeyCXYNGWAHZKOMJQ-UHFFFAOYSA-N
InChIInChI=1S/C22H17O3P/c23-21-16-20(22(24)25-21)26(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19/h1-15H,16H2
Canonical SMILESO=C(O1)C(CC1=O)=P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4
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分类

  • {SA} Anhydride Monomers, C-C Bond Formation, Chemical Synthesis, Materials Science, Monomers, Olefination, Polymer Science, Synthetic Reagents, Wittig Reagents
  • {SNA} Anhydride Monomers, C-C Bond Formation, Chemical Synthesis, Monomers, Olefination, Polymer Science, Synthetic Reagents, Wittig Reagents, 材料科学

相关文献及参考

  • Aldrich MSDS 1 , 1808:C / Corp MSDS 1 (2), 3521:A / FT-IR 2 (2), 3343:A / FT-IR 1 (2), 550:D / FT-NMR 1 (2), 1680:C / NMR-Reference 2 (2), 887:B / RegBook 1 (2), 2281:J / Structure Index 1 , 357:B:5

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition

其他信息

  • MOL 文件:906-65-0.mol
  • Sigma Aldrich:906-65-0(sigmaaldrich)
  • 2-(三苯基亚磷基)丁二酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 210530100 2-(三苯基亚磷基)丁二酸酐 2-(Triphenylphosphoranylidene)succinic anhydride 97% 10 GR 764元
  • Acros Organics:2-(Triphenylphosphoranylidene)succinic anhydride, 97%(906-65-0)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination

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