Tert-butyl 2-diazoacetate 2-重氮乙酸叔丁酯

CAS 35059-50-8 MFCD01318409

化学结构图

35059-50-8
SMILES: CC(C)(C)OC(=O)C=[N+]=[N-]

化学属性

Mol. FormulaC6H10N2O2
Mol. Weight142
Refractive indexn20/D 1.453(lit.)
Boiling Point51-53 °C/12 mmHg(lit.)
Density1.026 g/mL at 25 °C(lit.)

别名和识别编码

Chemical NameTert-butyl 2-diazoacetate
CAS Number35059-50-8
Synonym (tert-Butoxycarbonyl)diazomethane 2-Diazo-acetic Acid 1,1-Dimethylethyl Ester 2-Diazoacetic acid tert-butyl ester solution 重氮基乙酸叔丁酯 溶液 重氮基乙酸叔丁酯
PubChem Substance ID24871716
MDL NumberMFCD01318409
Chemical Name Translation2-重氮乙酸叔丁酯
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分类

  • {SNA} Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • An intermediate in the production of Zolpidem metabolites

相关文献及参考

  • Epple, R., et al.: Bioorg. Med. Chem. Lett., 16, 5488 (2006),
  • Klupsch, F., et al.: Chem. Pharm. Bull., 54, 1318 (2006),

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,T T
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H350 May cause cancer 可能致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P308+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
Signal word Danger
Safety Statements
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R38 Irritating to skin 刺激皮肤
  • R48/20
  • R45 May cause cancer 可能致癌
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Azo/Diazo Compounds - Nitrogen Compounds

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