2,4-Dibromothiazole 2,4-二溴噻唑

CAS 4175-77-3 MFCD01318994

化学结构图

4175-77-3
SMILES: Brc1csc(Br)n1

化学属性

Mol. FormulaC3HBr2NS
Mol. Weight242.92
Melting Point80-84°C
Density1.422
TSCANo
Boiling Point242.8°C at 760 mmHg

别名和识别编码

Chemical Name2,4-Dibromothiazole
CAS Number4175-77-3
Alfabeta NameDIBROMOTHIAZOLE 24-,
MDL NumberMFCD01318994
Synonym 2,4-Dibromothiazole {LY} 2,4-Dibromothiazole {} {LY} 2,4-Dibromothiazole {} {} {LY} 2,4-Dibromothiazole {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromothiazole {} {} {} {} {} {} {} {} {} {} {} {}
EC Number250-023-7
Beilstein Registry Number2384789
PubChem Substance ID2763297
Reaxys-RN507628
Chemical Name Translation2,4-二溴噻唑
LabNetwork Molecule IDLN00116357
InChIInChI=1S/C3HBr2NS/c4-2-1-7-3(5)6-2/h1H
Canonical SMILESBrC1=NC(Br)=CS1
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分类

  • Sulfur & Selenium Compounds
  • Heterocycles
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • {SNA} Building Blocks, C3 to C7, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiazoles
  • Aromatics

产品应用

  • 2,4-Dibromothiazole is an intermediate used in the preparation of various 2,4-disubstituted thiazole derivatives with biologically active properties such as survival motor neuron (SMN) protein modula

相关文献及参考

  • Xiao, J. et al.: J. Med. Chem., 54, 6215 (2011); Dash, J. et al.: Tetrahed. Lett., 52, 2246 (2011);

安全信息

Warnings IRRITANT, KEEP COLD
Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn Xn,Xi
Storage condition -20°C {LY} -20°C Keep Cold {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 下游产品:
  • Sigma Aldrich:4175-77-3(sigmaaldrich)
  • Acros Organics:2,4-Dibromothiazole, 97+%(4175-77-3)
  • MOL 文件:4175-77-3.mol
  • 2,4-二溴噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 5G 2160元 2011/04/16 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 25G 7320元 2011/04/16 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 1G 709元
  • 2,4-二溴噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 5G 2050元 2014/06/02 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 25G 6930元 2014/06/02 D3667 2,4-二溴噻唑 2,4-Dibromothiazole 1G 671元
  • 检测方法:HPLC
  • 用途一:用作有机合成中间体
  • Hazard Note:Harmful
  • 上游原料:氧溴化磷 --> 石脑油，原油
  • TCI Shanghai:2,4-二溴噻唑 2,4-Dibromothiazole,>;98.0%(GC)(4175-77-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazoles 噻唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazoles 噻唑
  5. C3 to C7 - Thiazoles

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