(S)-(-)-2-Bromopropionic acid (S)-(-)-2-溴丙酸
CAS 32644-15-8 MFCD00137325
化学结构图
SMILES: CC(Br)C(=O)O
化学属性
| Mol. Formula | C3H5BrO2 |
|---|---|
| Mol. Weight | 152.98 |
| Refractive index | 1.4740 to 1.4760 |
| Boiling Point | 94°C/11mmHg(lit.) |
| Density | 1.696 |
| Melting Point | -35 |
| Flash Point | 101°C(lit.) |
别名和识别编码
| Chemical Name | (S)-(-)-2-Bromopropionic acid |
|---|---|
| CAS Number | 32644-15-8 |
| Synonym | (S)-(-)-2-溴丙酸 {uni_hamburg} (S)-(-)-2-Bromopropionic acid S(-)-2-bromopropionic acid 2S-2-bromopropanoic acid ######## (S)-2-bromo-propionic acid S(-)-2-Brom-propionsäure (S)-(-)-2-Brompropionsäure |
| PubChem Substance ID | 87564652 |
| Beilstein Registry Number | 2,253 |
| MDL Number | MFCD00137325 |
| Reaxys-RN | 1720261 |
| Chemical Name Translation | (S)-(-)-2-溴丙酸 |
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分类
- {SNA} Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
- {uni_hamburg} no charge; carboxylic acid; chiral; 1fragment
- Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
产品应用
- (S)-2-Bromopropionic Acid is an intermediate in the synthesis of structural analogs of the antimitotic tripeptides hemiasterlins as antitumor agents.
相关文献及参考
- Gamble, W., et al.: Bioorg. Med. Chem., 7, 1611 (1999),
- 1. Tetrahedron Asymmetry 3 , 25, (1992)
- Beil. 2 ,253 / Beil. 2 ,IV,760
- FT-IR 2 (1), 793:C / RegBook 1 (1), 557:I / Structure Index 1 , 79:C:4
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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