2-Chloro-1,3-Dinitrobenzene 2-氯-1,3-二硝基苯

CAS 606-21-3 MFCD00014689

化学结构图

606-21-3
SMILES: O=[N+]([O-])c1cccc([N+](=O)[O-])c1Cl

化学属性

Mol. FormulaC6H3ClN2O4
Mol. Weight202.55
Density1.687
Melting Point86-88°C
TSCAYes
Boiling Point311.9°C at 760 mmHg
Flash Point315°C
Appearance 黄色针状结晶。熔点88℃，沸点315℃，相对密度1.6867（16/4℃）。溶于乙醇、乙醚，不溶于水。

别名和识别编码

Chemical Name2-Chloro-1,3-Dinitrobenzene
Synonym 2-Chloro-1,3-dinitrobenzene {LY} 2-Chloro-1,3-dinitrobenzene {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Chloro-1,3-dinitrobenzene {} {} {} {} {} {} {} {
MDL NumberMFCD00014689
CAS Number606-21-3
EC Number210-107-6
Merck Number14,2137
Beilstein Registry Number522187
Alfabeta NameCHLORODINITROBENZENE 213---,
Chemical Name Translation2-氯-1,3-二硝基苯
LabNetwork Molecule IDLN00010373
Canonical SMILESClC1=C([N+]([O-])=O)C=CC=C1[N+]([O-])=O
PubChem Substance ID11814
InChIInChI=1S/C6H3ClN2O4/c7-6-4(8(10)11)2-1-3-5(6)9(12)13/h1-3H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different br

安全信息

RTECSCZ0525500
Safety Statements
Packing GroupII
UN Number
Risk Statements
Warnings IRRITANT
Hazard Class6.1
Signal word
GHS Symbol
Hazard Codes
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P302+P352
  • P304+P340
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H330 Fatal if inhaled 吸入致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

其他信息

  • MOL 文件:606-21-3.mol
  • MSDS 信息:1-Chloro-2,6-dinitrobenzene(606-21-3).msds
  • 上游原料:硝酸 --> 氯化亚铜 --> 氯苯 --> 2,6-二硝基苯胺
  • 下游产品:二甲戊灵
  • Alfa Aesar:2-氯-1,3-二硝基苯,98+% 2-Chloro-1,3-dinitrobenzene, 98+%(606-21-3)
  • 方法一:由2,6-二硝基苯胺经重氮化、置换而得。将亚硝酸钠加入浓硫酸中，搅拌，加热至70℃，待全部溶解后，将溶液冷却至25-30℃。慢慢加入2,6-二硝基苯胺和冰醋酸配制的溶液，控制加入速度，使反应温度在40℃以上。加完后在40℃搅拌半小时。然后加入经过预冷的氯化亚铜浓盐酸溶液，反应放热，并产生气泡。当反应变得缓和时，加热至80℃、20min后停止冒气泡。加入等体积的水，冷却，过滤，水洗，干燥，用乙酸重结晶，得2,6-二硝基氯苯。收率约70%。
  • 2,6-二硝基氯苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L04593 2-氯-1,3-二硝基苯, 98+% 2-Chloro-1,3-dinitrobenzene, 98+% 5g 1946元 2010/05/25 L04593 2-氯-1,3-二硝基苯, 98+% 2-Chloro-1,3-dinitrobenzene, 98+% 1g 491元
  • 用途二:用作有机合成中间体及分析试剂。
  • 用途一:用于制备硫化染料

系列性分类

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